Conformational fluxionality of long-chain alkene clusters in the gas phase evidenced from a combined experimental and theoretical approach.

Clusters bound by weak, non-covalent forces, such as van der Waals interactions and hydrogen bonds, are ubiquitous in dilute media ranging from aerosols to molecular fluids and biological structures, their interest being not only fundamental as in astrochemistry but also more applied as in organic electronics. Neutral clusters of up to six 1-hexene molecules produced by supersonic expansion of a gas mixture were ionized, mass selected, and spectroscopically characterized using synchrotron-based VUV photoelectron photoion coincidence technique. Ionization energies inferred from these measurements show decreasing trends as the cluster size increases, by about 0.

Debunking Three Myths About Misinformation.

Recent years have seen a surge in research on why people fall for misinformation and what can be done about it. Drawing on a framework that conceptualizes truth judgments of true and false information as a signal-detection problem, the current article identifies three inaccurate assumptions in the public and scientific discourse about misinformation: (1) People are bad at discerning true from false information, (2) partisan bias is not a driving force in judgments of misinformation, and (3) gullibility to false information is the main factor underlying inaccurate beliefs. Counter to these assumptions, we argue that (1) people are quite good at discerning true from false information, (2) partisan bias in responses to true and false information is pervasive and strong, and (3) skepticism against belief-incongruent true information is much more pronounced than gullibility to belief-congruent false information.

The role of intramolecular hydrogen bonding in photoelectron circular dichroism: the diastereoisomers of 1-amino-2-indanol.

(1,2)--Aminoindanol and (1,2)--aminoindanol, denoted as -AI and -AI, are diastereoisomer aromatic aminoalcohols differing by the presence of a weak intramolecular hydrogen bond in -AI, which is absent in -AI. They also differ by the number of conformers under supersonic jet conditions, one for -AI and two for -AI. One-photon and resonance-enhanced two-photon photoelectron circular dichroism (PECD) spectra are obtained for the two molecules.

Conformational effects in the identification and quantification of ketohydroperoxides in the oxidation of -pentane.

Stereochemistry plays a key role in both fundamental chemical processes and the dynamics of a large set of molecular systems of importance in chemistry, medicine and biology. Predicting the chemical transformations of organic precursors in such environments requires detailed kinetic models based on laboratory data. Reactive intermediates play a critical role in constraining the models but their identification and especially their quantification remain challenging.