The dynamics of molecular associates in a methanol/water mixture was investigated using quasielastic neutron scattering. By measuring the signal from four methanol/water samples differing only by their isotopic composition, the relative motion of the water to methanol molecules, their mutual dynamics, was determined at the nanoscale. The thus obtained nanoscopic mutual diffusion coefficient signals a significantly slower process than the single particle diffusion of either methanol or water in the system as well as their macroscopic mutual diffusion.
View Article and Find Full Text PDFWe use neutron scattering to investigate spin excitations in , which has a -axis incommensurate helical structure of the two-dimensional (2D) in-plane ferromagnetic (FM) ordered layers for . By comparing the wave vector and energy dependent spin excitations in helical ordered and paramagnetic , we find that Ni doping, while increasing lattice disorder in , enhances quasi-2D FM spin fluctuations. However, our band structure calculations within the combined density functional theory and dynamic mean field theory (DFT+DMFT) failed to generate a correct incommensurate wave vector for the observed helical order from nested Fermi surfaces.
View Article and Find Full Text PDFCrAs is a well-known helimagnet with the double-helix structure originating from the competition between the Dzyaloshinskii-Moriya interaction (DMI) and antiferromagnetic exchange interaction . By resonant soft-x-ray scattering, we observe the magnetic peak (0 0 ) that emerges at the helical transition with ≈ 267.5 K.
View Article and Find Full Text PDFTrilayer nickelates, which exhibit a high degree of orbital polarization combined with an electron count (d^{8.67}) corresponding to overdoped cuprates, have been identified as a promising candidate platform for achieving high-T_{c} superconductivity. One such material, La_{4}Ni_{3}O_{8}, undergoes a semiconductor-insulator transition at ∼105 K, which was recently shown to arise from the formation of charge stripes.
View Article and Find Full Text PDFWe present neutron-diffraction data for the cubic-heavy-fermion YbBiPt that show broad magnetic diffraction peaks due to the fragile short-range antiferromagnetic (AFM) order persist under an applied magnetic-field . Our results for and a temperature of show that magnetic diffraction peak can be described by the same two-peak line shape found for below the Néel temperature of . Both components of the peak exist for , which is well past the AFM phase boundary determined from our new resistivity data.
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