Proc Natl Acad Sci U S A
August 2024
We study the coupled charge density wave (CDW) and insulator-to-metal transitions in the 2D quantum material 1T-TaS. By applying in situ cryogenic 4D scanning transmission electron microscopy with in situ electrical resistance measurements, we directly visualize the CDW transition and establish that the transition is mediated by basal dislocations (stacking solitons). We find that dislocations can both nucleate and pin the transition and locally alter the transition temperature by nearly ~75 K.
View Article and Find Full Text PDFMott metal-insulator transitions possess electronic, magnetic, and structural degrees of freedom promising next-generation energy-efficient electronics. A previously unknown, hierarchically ordered, and anisotropic supercrystal state is reported and its intrinsic formation characterized in-situ during a Mott transition in a CaRuO thin film. Machine learning-assisted X-ray nanodiffraction together with cryogenic electron microscopy reveal multi-scale periodic domain formation at and below the film transition temperature (T ≈ 200-250 K) and a separate anisotropic spatial structure at and above T.
View Article and Find Full Text PDFIt has been suggested that BaInOmight be a high-superconductor. Experimental investigation of the properties of BaInOwas long inhibited by its instability in air. Recently epitaxial BaInOwith a protective capping layer was demonstrated, which finally allows its electronic characterization.
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