Publications by authors named "L Dutruch"

Assessing the fate of contaminants in the environment requires a deep understanding of intrinsic adsorption mechanisms on natural minerals such as Fe-oxyhydroxides. In this study, we proposed an innovative approach to probe site heterogeneities on the goethite surface by comparing the adsorption behavior of rare earth elements (REEs, including Sc, Y, and all lanthanides; Ln) except Pm, as well as Th and U. A surface loading-dependent adsorption of Ln and Y was observed, with a shift from (i) preferential middle to heavy REE adsorption and (ii) limited to substantial fractionation between Y and Ho as the loading increased.

View Article and Find Full Text PDF
Article Synopsis
  • Research shows that the mobility of rare earth elements (REEs) in the environment is influenced by colloids, particularly iron-organic colloids (Fe-OM), which come in both large and small sizes.
  • A study using advanced techniques found that Fe-OM nano-colloids, around 25 nm in diameter, can aggregate more at lower pH levels and significantly change size when interacting with REEs, especially heavy REEs that form strong complexes.
  • The addition of calcium enhances the aggregation of these nano-colloids by neutralizing their charges, suggesting that REEs can influence their own movement and the transfer of colloids in the environment.
View Article and Find Full Text PDF

Most studies on nanoplastics (NPs) focus on aquatic environments, overlooking their combined bioaccumulation with pollutants in terrestrial ecosystems. This study addresses a part of this gap by investigating how polystyrene nanoplastics (PS-NPs) affect the bioaccumulation and translocation of lead (Pb) in Hordeum vulgare L. plants.

View Article and Find Full Text PDF

Effective, post-accidental management needs an accurate understanding of the biogeochemical behavior of radionuclides in surface environments at a regional scale. Studies on stable isotopes (element homologs) can improve this knowledge. This work focuses on the biogeochemical behavior of stable cesium (Cs) along a major European fluvial-estuarine system, the Gironde Estuary (SW France).

View Article and Find Full Text PDF

Rare earth elements (REE) are highly sought after for advanced technology, in response concerns about their environmental impact have arisen. The mobility and transport of REEs are influenced by their binding to solid surfaces, particularly colloids. With the widespread occurrence of REEs and their potential increase due to climate change, there is growing interest in understanding colloids composed of organic matter (OM) and iron (Fe).

View Article and Find Full Text PDF