This work presents observations of symmetry breakages in the intensity distributions of near-zone-axis convergent-beam electron diffraction (CBED) patterns that can only be explained by the symmetry of the specimen and not the symmetry of the unit cell describing the atomic structure of the material. The specimen is an aluminium-copper-tin alloy containing voids many tens of nanometres in size within continuous single crystals of the aluminium host matrix. Several CBED patterns where the incident beam enters and exits parallel void facets without the incident beam being perpendicular to these facets are examined.
View Article and Find Full Text PDFDespite the clinical benefits that chemotherapeutics has had on the treatment of breast cancer, drug resistance remains one of the main obstacles to curative cancer therapy. Nanomedicines allow therapeutics to be more targeted and effective, resulting in enhanced treatment success, reduced side effects, and the possibility of minimising drug resistance by the co-delivery of therapeutic agents. Porous silicon nanoparticles (pSiNPs) have been established as efficient vectors for drug delivery.
View Article and Find Full Text PDFMany new circular economy technologies are gaining momentum, yet research on the complexity of adoption decisions driven by uncertainties, both at technology and ecosystem level, is lacking. In the present study, an agent-based model was developed to study factors that influence the adoption of emerging circular technologies. The case of the waste treatment industry was chosen, specifically its (non-) adoption of the so-called "Volatile Fatty Acid Platform", a circular economy technology that facilitates both the valorization of organic waste into high-end products as well as their sale on global markets.
View Article and Find Full Text PDFInspired by nature, green chemistry uses various biomolecules, such as proteins, as reducing agents to synthesize metallic nanostructures. This methodology provides an alternative route to conventional harsh synthetic processes, which include polluting chemicals. Tuning the resulting nanostructure properties, such as their size and shape, is challenging as the exact mechanism involved in their formation is still not well understood.
View Article and Find Full Text PDFNickel oxide exhibits almost the highest theoretical specific capacitance ( ), which includes contributions from non-faradaic double layer charging and faradaic OH adsorption. However, the realistic and tangible is due to the faradaic process, which can be influenced by chemical ( stoichiometry) and structural ( grain size) changes. Hence, it is necessary to investigate the interrelationships among chemical and structural features and charge storage capacity.
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