Publications by authors named "L Bayarjargal"
Magnesium and calcium carbonate minerals are significant reservoirs of Earth's carbon and understanding their behavior under different conditions is crucial for elucidating the mechanisms of deep carbon storage. Huntite, MgCa(CO), is one of the two stable calcium magnesium carbonate phases, together with dolomite. The distinctive cation coordination environment of Ca atoms compared to calcite-type and dolomite structures makes huntite a comparatively less dense phase.
View Article and Find Full Text PDFWe have synthesized the first hydrous sp-carbonate by laser-heating Ba[CO], CO and HO in a diamond anvil cell at 40(3) GPa. The crystal structure of Ba[HCO][HCO][HCO][HCO] was determined by synchrotron single crystal X-ray diffraction. The experiments were complemented by DFT-based calculations.
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- Researchers synthesized anhydrous pyrocarbonate and the first hydrogen pyrocarbonate Li[HCO] using a laser-heated diamond anvil cell at moderate pressures (around GPa).
- The structures of these compounds were analyzed through single crystal X-ray diffraction, complemented by Raman spectroscopy and DFT calculations for a deeper understanding of their properties.
- The discovery of the hydrogenated pyrocarbonate Li[HCO] adds to the family of inorganic pyrocarbonates, showcasing a unique O-H-O structure that transitions to a conventional O-H···O hydrogen bond when pressure is released.
An entire series of mercury cyanamides/carbodiimides, including two new materials─Hg(NCN)Cl (, = 4, = 9.109(1) Å, = 15.386(1) Å, = 8.
View Article and Find Full Text PDFWe synthesized an iron carbonate, Fe[CO], by reacting FeO with CO at high temperatures and pressures of approximately 33(3) GPa. The structure was solved by single-crystal X-ray diffraction. Full geometry optimizations based on density functional theory reproduced the crystal structure.
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