Breakdown of the Quantum Distinction of Regular and Chaotic Classical Dynamics in Dissipative Systems.

Quantum chaos has recently received increasing attention due to its relationship with experimental and theoretical studies of nonequilibrium quantum dynamics, thermalization, and the scrambling of quantum information. In an isolated system, quantum chaos refers to properties of the spectrum that emerge when the classical counterpart of the system is chaotic. However, despite experimental progress leading to longer coherence times, interactions with an environment can never be neglected, which calls for a definition of quantum chaos in dissipative systems.

Portuguese Society of Ophthalmology and Portuguese Society of Human Genetics Joint Clinical Practice Guidelines for Genetic Testing in Inherited Retinal Dystrophies.

The Portuguese Society of Ophthalmology and the Portuguese Society of Human Genetics developed clinical practice guidelines to streamline genetic testing for inherited retinal dystrophies (IRDs), underlining the critical role of molecular diagnosis in enhancing patient care. Genetic testing is pivotal in diagnosis, genetic counselling, prognosis and access to clinical trials, and new gene-specific therapies. These guidelines recommend genetic testing in all IRD patients and provide a detailed assessment of available testing methods, ensuring that genetic counselling is integrated into ophthalmic care.

Hydrogen Production by the Ruthenium(II) Complex Bearing a Bulky PNP Ligand: A Catalyst for the Decomposition of Formic Acid and/or Ammonium Formate.

The five-coordinate complex [RuCl(PNP)] () was synthesized from the binuclear [RuCl(-cym)] with a PNP-type ligand (PNP = 3,6-di--butyl-1,8-bis(dipropylphosphino)methyl)-9-carbazole - (Cbzdiphos )H) in a toluene solution, within 20 h at 110 °C, producing a green solid, which was precipitated with a 1/1 mixture of - pentane/HMDSO. The complex was characterized by NMR-H, C, and P{H}, mass spectroscopy-LIFDI, FTIR, UV/vis spectroscopy, and cyclic voltammetry, as well as a description of the optimized structure by DFT calculation. The reactivity of was investigated in the presence of potassium triethylborohydride (KBEtH, in THF solution of 1.

Active Commuting in Brazil: A Systematic Review and Meta-Analysis of Proportions.

Background: Active commuting benefits both individual and planetary health. Estimating commuting behavior is desirable, although very challenging in large and regionally relevant nations like Brazil.

Methods: This review (CRD42023431054) included observational studies that estimated prevalence of active commuting in Brazil for adults (≥18 y).

Freezing of gait shapes the postural control of individuals with Parkinson's disease: Effect of visual information and medication states.

Background: Several measures of the center of pressure have been used to describe magnitude and structure of the postural sway in individuals with Parkinson's disease (PD). This study aimed to examine whether both the magnitude and structure of the center of pressure trajectory can differentiate PD individuals with and without freezing of gait in both On- and Off-medication states and with eyes open and closed.

Methods: Twenty-four individuals with PD (14 without and 10 with freezing of gait) were tested.