The demand for fast-charging lithium-ion batteries (LIBs) with long cycle life is growing rapidly due to the increasing use of electric vehicles (EVs) and energy storage systems (ESSs). Meeting this demand requires the development of advanced anode materials with improved rate capabilities and cycling stability. Graphite is a widely used anode material for LIBs due to its stable cycling performance and high reversibility.
View Article and Find Full Text PDFThe use of lithium metal anodes in solid-state batteries has emerged as one of the most promising technologies for replacing conventional lithium-ion batteries. Solid-state electrolytes are a key enabling technology for the safe operation of lithium metal batteries as they suppress the uncontrolled growth of lithium dendrites. However, the mechanical properties and electrochemical performance of current solid-state electrolytes do not meet the requirements for practical applications of lithium metal batteries.
View Article and Find Full Text PDFA rechargeable lithium-oxygen battery (LOB) operates via the electrochemical formation and decomposition of solid-state LiO on the cathode. The rational design of the cathode nanoarchitectures is thus required to realize high-energy-density and long-cycling LOBs. Here, we propose a cathode nanoarchitecture for LOBs, which is composed of mesoporous carbon (MPC) integrated with carbon nanotubes (CNTs).
View Article and Find Full Text PDFThe realisation of fast-charging lithium-ion batteries with long cycle lifetimes is hindered by the uncontrollable plating of metallic Li on the graphite anode during high-rate charging. Here we report that surface engineering of graphite with a cooperative biphasic MoO-MoP promoter improves the charging rate and suppresses Li plating without compromising energy density. We design and synthesise MoO-MoP/graphite via controllable and scalable surface engineering, i.
View Article and Find Full Text PDFThe use of solid electrolytes provides a technical solution to address the safety issues of lithium-ion batteries and enables a bipolar design of high-voltage and high-energy battery modules. The bipolar design avoids unnecessary components and parts for packaging and electrical connection; therefore, it facilitates an increase in the volumetric energy density of the battery, while enabling easy build-up of total output voltage. Herein, the design and construction of a multilayered, bipolar-type, all-solid-state battery (ASSB) from a biphasic solid electrolyte (BSE) based on inorganic Li La TiO perovskite and poly(ethylene oxide) (PEO) are reported.
View Article and Find Full Text PDFAll-solid-state lithium batteries offer notable advantages over conventional Li-ion batteries with liquid electrolytes in terms of energy density, stability, and safety. To realize this technology, it is critical to develop highly reliable solid-state inorganic electrolytes with high ionic conductivities and adequate processability. Li Al Ti (PO ) (LATP) with a NASICON (Na superionic conductor)-like structure is regarded as a potential solid electrolyte, owing to its high "bulk" conductivity (ca.
View Article and Find Full Text PDFThere is a great deal of current interest in the development of rechargeable sodium (Na)-ion batteries (SIBs) for low-cost, large-scale stationary energy storage systems. For the commercial success of this technology, significant progress should be made in developing robust anode (negative electrode) materials with high capacity and long cycle life. Sn-P compounds are considered promising anode materials that have considerable potential to meet the required performance of SIBs, and they have been typically prepared by high-energy mechanical milling.
View Article and Find Full Text PDFSodium (Na)-ion batteries (NIBs) have attracted significant interest as an alternative chemistry to lithium (Li)-ion batteries for large-scale stationary energy storage systems. Discovering high-performance anode materials is a great challenge for the commercial success of NIB technology. Transition metal oxides with tailored nanoarchitectures have been considered as promising anodes for NIBs due to their high capacity.
View Article and Find Full Text PDFRechargeable metal-air batteries are considered a promising energy storage solution owing to their high theoretical energy density. The major obstacles to realising this technology include the slow kinetics of oxygen reduction and evolution on the cathode (air electrode) upon battery discharging and charging, respectively. Here, we report non-precious metal oxide catalysts based on spinel-type manganese-cobalt oxide nanofibres fabricated by an electrospinning technique.
View Article and Find Full Text PDFRechargeable lithium-oxygen (Li-O2) batteries have higher theoretical energy densities than today's lithium-ion batteries and are consequently considered to be an attractive energy storage technology to enable long-range electric vehicles. The main constituents comprising a cathode of a lithium-oxygen (Li-O2) battery, such as carbon and binders, suffer from irreversible decomposition, leading to significant performance degradation. Here, carbon- and binder-free cathodes based on nonprecious metal oxides are designed and fabricated for Li-O2 batteries.
View Article and Find Full Text PDFA quasi-solid-state lithium-oxygen battery constructed using a gel polymer electrolyte with an ionic liquid is proposed. The battery architecture incorporates a design feature that can be easily scaled up in size for use in large systems. The feasibility study demonstrates that the battery operates successfully for repeated discharge-charge cycles.
View Article and Find Full Text PDFRechargeable metal-air batteries have attracted a great interest in recent years because of their high energy density. The critical challenges facing these technologies include the sluggish kinetics of the oxygen reduction-evolution reactions on a cathode (air electrode). Here, we report doped lanthanum nickelates (La2NiO4) with a layered perovskite structure that serve as efficient bifunctional electrocatalysts for oxygen reduction and evolution in an aqueous alkaline electrolyte.
View Article and Find Full Text PDFCarbon-free cobalt oxide cathodes for lithium-oxygen batteries are fabricated via an electrodeposition-conversion process. The Co3O4-only cathodes show a remarkably reduced voltage gap (by ca. 550 mV compared to the carbon-only cathode) as well as excellent long-term cyclability.
View Article and Find Full Text PDFThe Jervell and Lange-Nielsen syndrome (JLNS) is an autosomal recessive syndrome characterized by congenital deafness and cardiac phenotype (QT prolongation, ventricular arrhythmias, and sudden death). JLNS has been shown to occur due to homozygous mutation in KCNQ1 or KCNE1. There have been a few clinical case reports on JLNS in Korea; however, these were not confirmed by a genetic study.
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