Enhanced extraction of methylene blue by dodecyl-methyl imidazolium dodecyl sulfate GUMBOS - magnetic alginate beads.

In this study, dodecyl-methyl imidazolium dodecyl sulfonate ([CMIm][DS]) GUMBOS were synthesized and incorporated into alginate with γ-FeO to fabricate magnetic adsorbent beads ([C₁₂MIm][DS]-beads) for methylene blue (MB) removal. Characterization via ESI-MS, FT-IR, SEM, BET, and TGA confirmed their structure and properties. The beads achieved a maximum adsorption capacity of 4.

Influence of humidity on accuracy of QCM - IR780-based GUMBOS sensor arrays.

Herein, hydrophobic coating materials are reported for QCM detection of VOCs under dry and humid conditions. In this study, IR780-based GUMBOS ([IR780][OTf] and [IR780][NTf2]) were synthesized using an ion exchange reaction and the anions trifluoromethanesulfonimide ([OTf]) and bisperfluoromethanesulfonimide ([NTf2]). The parent iodide salts and GUMBOS ([IR780][I]), [IR780][OTf], and [IR780][NTf2]) were characterized using several analytical techniques.

Strategies and Considerations for Least-Squares Analysis of Total Scattering Data.

The process of least-squares analysis has been applied for decades in the field of crystallography. Here, we discuss the application of this process to total scattering data, primarily in the combination of least-squares Rietveld refinements and fitting of the atomic pair distribution function (PDF). While these two approaches use the same framework, the interpretation of results from least-squares fitting of PDF data should be done with caution through carefully constructed analysis approaches.