Energetic plasticizers are being sought for their use in energetic formulations when combined with explosives. An energetic plasticizer based on the insensitive highly explosive 3-amino-5-nitro-l,2,4-triazole (ANTA) was synthesized and characterized by spectroscopy, X-ray crystallography, thermal analyses, and safety testing. Lastly, density functional theory calculations were employed to examine the observed selectivity among the three nucleophilic ring nitrogen atoms of ANTA toward electrophiles such as ANTA acrylate; this selectivity was found to be a combination of steric, electronic, and hydrogen bonding effects.
View Article and Find Full Text PDFWe present a new integrated experimental and modeling effort that assesses the intrinsic sensitivity of energetic materials based on their reaction rates. The High Explosive Initiation Time (HEIT) experiment has been developed to provide a rapid assessment of the high-temperature reaction kinetics for the chemical decomposition of explosive materials. This effort is supported theoretically by quantum molecular dynamics (QMD) simulations that depict how different explosives can have vastly different adiabatic induction times at the same temperature.
View Article and Find Full Text PDFPentaerythritol tetranitrate (PETN) has been used extensively in commercial detonators and other explosive applications for many decades. Here, we show the results of a comprehensive 1.5 year aging study of PETN in commercial detonators, addressing batch-to-batch variations, surface area changes, and comparisons of aged loose powders side-by-side with identically aged detonators.
View Article and Find Full Text PDFThere are few techniques available for chemists to obtain time-to-explosion data with known temperature inputs at the early stages of the design and synthesis of new explosives. In the 1960s, a technique was developed to rapidly heat milligram-quantities of confined explosives to ∼1000 K on microsecond timescales. Wenograd [Trans.
View Article and Find Full Text PDFHere we report the synthesis and characterization of diiron complexes containing triaryl N and NS ligands derived from -phenylenediamine. The complexes display significant differences in Fe-Fe distances and magnetic properties that depend on the identity of the flanking NMe and SMe donor groups.
View Article and Find Full Text PDFDetermining the factors that influence and can help predict energetic material sensitivity has long been a challenge in the explosives community. Decades of literature reports identify a multitude of factors both chemical and physical that influence explosive sensitivity; however no unifying theory has been observed. Recent work by our team has demonstrated that the kinetics of "trigger linkages" (, the weakest bonds in the energetic material) showed strong correlations with experimental drop hammer impact sensitivity.
View Article and Find Full Text PDFMetal-ligand cooperativity (MLC), a phenomenon that leverages reactive ligands to promote synergistic reactions with metals, has proven to be a powerful approach to achieving new and unprecedented chemical transformations with metal complexes. While many examples of MLC are known with a wide range of substrates, experimentally quantifying how ligand modifications affect MLC binding strength remains a challenge. Here we describe how cyclic voltammetry (CV) was used to quantify differences in MLC binding strength in a series of square-pyramidal Ru complexes.
View Article and Find Full Text PDFMetal-ligand cooperativity (MLC) relies on chemically reactive ligands to assist metals with small-molecule binding and activation, and it has facilitated unprecedented examples of catalysis with metal complexes. Despite growing interest in combining ligand-centered chemical and redox reactions for chemical transformations, there are few studies demonstrating how chemically engaging redox active ligands in MLC affects their electrochemical properties when bound to metals. Here we report stepwise changes in the redox activity of model Ru complexes as zero, one, and two BH molecules undergo MLC binding with a triaryl noninnocent NS ligand derived from -phenylenediamine ().
View Article and Find Full Text PDFThe continued development of redox-active ligands requires an understanding as to how ligand modifications and related factors affect the locus of redox activity and spin density in metal complexes. Here we describe the synthesis, characterization, and electronic structure of nickel complexes containing triaryl NNNN () and SNNS () ligands derived from -phenylenediamine. The tetradentate ligands in and were investigated and compared to those in metal complexes with compositionally similar ligands to determine how ligand-centered redox properties change when redox-active flanking groups are replaced with redox-innocent NMe or SMe.
View Article and Find Full Text PDFBond distance is a common structural metric used to assess changes in metal-ligand bonds, but it is not clear how sensitive changes in bond distances are with respect to changes in metal-ligand covalency. Here we report ligand K-edge XAS studies on Ni and Pd complexes containing different phosphorus(III) ligands. Despite the large number of electronic and structural permutations, P K-edge pre-edge peak intensities reveal a remarkable correlation that spectroscopically quantifies the linear interdependence of covalent M-P σ bonding and bond distance.
View Article and Find Full Text PDFConstraining σ -P compounds in nontrigonal, entatic geometries has proven to be an effective strategy for promoting biphilic oxidative addition reactions more typical of transition metals. Although qualitative descriptions of the impact of structure and symmetry on σ -P complexes have been proposed, electronic structure variations responsible for biphilic reactivity have yet to be elucidated experimentally. Reported here are P K-edge XANES data and complementary TDDFT calculations for a series of structurally modified P(N) complexes that both validate and quantify electronic structure variations proposed to give rise to biphilic reactions at phosphorus.
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