Renewable Resources as Promising Materials for Obtaining Graphene Oxide-like Structures.

Currently, one of the topical directions in the field of production and application of graphene-like nanostructures is the use of renewable natural raw materials, which have unlimited resources for an economically efficient large-scale yield of a product with environmental safety. In this regard, we present the production of graphene oxide (GO) from a renewable natural raw material of plant biomass, birch activated carbon (BAC), and a comparison of the obtained physicochemical, mechanical, and electrical properties of birch activated carbon-graphene oxide (BAC-GO) and graphite-graphene oxide (G-GO) synthesized from the initial materials, BAC and graphite (G). Results obtained from this study confirm the successful oxidation of BAC, which correlates well with the physical-chemical dates of the G-GO and BAC-GO samples.

Boulton-Katritzky Rearrangement of 5-Substituted Phenyl-3-[2-(morpholin-1-yl)ethyl]-1,2,4-oxadiazoles as a Synthetic Path to Spiropyrazoline Benzoates and Chloride with Antitubercular Properties.

The analysis of stability of biologically active compounds requires an accurate determination of their structure. We have found that 5-aryl-3-(2-aminoethyl)-1,2,4-oxadiazoles are generally unstable in the presence of acids and bases and are rearranged into the salts of spiropyrazolinium compounds. Hence, there is a significant probability that it is the rearranged products that should be attributed to biological activity and not the primarily screened 5-aryl-3-(2-aminoethyl)-1,2,4-oxadiazoles.