Influence of Mechanical Fatigue at Different States of Charge on Pouch-Type Li-Ion Batteries.

Since flexible devices are being used in various states of charge (SoCs), it is important to investigate SoCs that are durable against external mechanical deformations. In this study, the effects of a mechanical fatigue test under various initial SoCs of batteries were investigated. More specifically, ultrathin pouch-type Li-ion polymer batteries with different initial SoCs were subjected to repeated torsional stress and then galvanostatically cycled 200 times.

Binder-free and high-loading sulfurized polyacrylonitrile cathode for lithium/sulfur batteries.

Sulfurized polyacrylonitrile (SPAN) is a promising active material for Li/S batteries owing to its high sulfur utilization and long-term cyclability. However, because SPAN electrodes are synthesized using powder, they require large amounts of electrolyte, conducting agents, and binder, which reduces the practical energy density. Herein, to improve the practical energy density, we fabricated bulk-type SPAN disk cathodes from pressed sulfur and polyacrylonitrile powders using a simple heating process.

Knowledge extraction of sonophotocatalytic treatment for acid blue 113 dye removal by artificial neural networks.

Removing decolorizing acid blue 113 (AB113) dye from textile wastewater is challenging due to its high stability and resistance to removal. In this study, we used an artificial neural network (ANN) model to estimate the effect of five different variables on AB113 dye removal in the sonophotocatalytic process. The five variables considered were reaction time (5-25 min), pH (3-11), ZnO dosage (0.

Ultrahigh-rate nickel monosulfide anodes for sodium/potassium-ion storage.

Transition-metal sulfides have been extensively studied as anode materials for use in sodium-ion batteries (SIBs) and potassium-ion batteries (PIBs) due to their multi-electron reactions, high rate performance, and abundant available resources. However, the practical capacities of metal sulfides remain low due to conductivity issues, volume expansion, and the use of traditional carbonate electrolytes. To overcome these drawbacks, ether electrolytes can be combined with nanoparticle-based metal sulfide anodes.

Prediction of batch sorption of barium and strontium from saline water.

Celestite and barite formation results in contamination of barium and strontium ions hinder oilfield water purification. Conversion of bio-waste sorbent products deals with a viable, sustainable and clean remediation approach for removing contaminants. Biochar sorbent produced from rice straw was used to remove barium and strontium ions of saline water from petroleum industries.

High power NaV(PO) symmetric full cell for sodium-ion batteries.

Sodium-ion batteries (SIBs) are a viable substitute for lithium-ion batteries due to the low cost and wide availability of sodium. However, practical applications require the development of fast charging sodium-ion-based full-cells with high power densities. NaV(PO) (NVP) is a bipolar material with excellent characteristics as both a cathode and an anode material in SIBs.

Free-Standing NiS₂ Electrode as High-Rate Anode Material for Sodium-Ion Batteries.

Owing to the speculated price hike and scarcity of lithium resources, sodium-ion batteries are attracting significant research interest these days. However, sodium-ion battery anodes do not deliver good electrochemical performance, particularly rate performance. Herein, we report the facile electrospinning synthesis of a free-standing nickel disulfide (NiS²) embedded on carbon nanofiber.

Synthesis and Electrochemical Properties of MoS₂/rGO/S Composite as a Cathode Material for Lithium-Sulfur Batteries.

To develop the next-generation energy storage systems, lithium-sulfur batteries represent an attractive option due to its high theoretical capacity, and energy density. In this work, MoS₂/rGO (reduced graphene oxide) was prepared by hydrothermal synthesis and sulfur added by the melt diffusion method. The as-prepared MoS₂/rGO has strong polysulfides entrapping, high conductivity, large surface area, and high catalytic activity, consequently resulting in enhanced rate performance and cycling capability of Li-S batteries.

Effect of Ordered Carbon Structures on Electrochemical Properties of Carbon/Sulfur Composites in Lithium-Sulfur Batteries.

In this paper, the relationship between the pore spatial structures, pore sizes, and pore types of highly ordered mesoporous CMK-based carbons (CMK-1, CMK-3, and CMK-5) and their electrochemical performance in Li-S batteries is investigated. CMK-1 has a complex spatial structure and small pores. The structure is good for limiting polysulfide in the pores, but not for rapid transfer of Li ions in the cell.

Controlling the Voltage Window for Improved Cycling Performance of SnO₂ as Anode Material for Lithium-Ion Batteries.

Transition metal oxide materials with high theoretical capacities have been studied as substitutes for commercial graphite in lithiumion batteries. Among these, SnO₂ is a promising alloying reaction-based anode material. However, the problem of rapid capacity fading in SnO₂ due to volume variation during the alloying/dealloying processes must be solved.

Hydrothermal Synthesis and Electrochemical Behavior of the SnO₂/rGO as Anode Materials for Lithium-Ion Batteries.

In this work, the hydrothermal method was employed to produce SnO₂/rGO as anode material. Nanostructured SnO₂ was prepared to enhance reversibility and to deal with the undesirable volume changes during cycling. The SnO₂/rGO hybrid exhibits long cycle life in lithium-ion storage capacity and rate capability with an initial discharge capacity of 1327 mAh/g at 0.

Fabrication of Nickel Sulfide/Nitrogen-Doped Reduced Graphene Oxide Nanocomposite as Anode Material for Lithium-Ion Batteries and Its Electrochemical Performance.

In this study, NiS/graphene nanocomposites were synthesized by simple heat treatment method of three graphene materials (graphene oxide (GO), reduced graphene oxide (rGO) and nitrogen-doped graphene oxide (N-rGO)) and NiS precursor. The morphology and crystal structure of NiS/graphene nanocomposites were characterized using field emission scanning electron microscope (FE-SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Electrochemical properties were also investigated.

Boosting High Energy Density Lithium-Ion Storage via the Rational Design of an FeS-Incorporated Sulfurized Polyacrylonitrile Fiber Hybrid Cathode.

In order to satisfy the escalating energy demands, it is inevitable to improve the energy density of current Li-ion batteries. As the development of high-capacity cathode materials is of paramount significance compared to anode materials, here we have designed for the first time a unique synergistic hybrid cathode material with enhanced specific capacity, incorporating cost-effective iron sulfide (FeS) nanoparticles in a sulfurized polyacrylonitrile (SPAN) nanofiber matrix through a rational in situ synthesis strategy. Previous reports on FeS cathodes are scarce and consist of an amorphous carbon matrix to accommodate the volume changes encountered during the cycling process.

An Electrospun Core-Shell Nanofiber Web as a High-Performance Cathode for Iron Disulfide-Based Rechargeable Lithium Batteries.

FeS /C core-shell nanofiber webs were synthesized for the first time by a unique synthesis strategy that couples electrospinning and carbon coating of the nanofibers with sucrose. The design of the one-dimensional core-shell morphology was found to be greatly beneficial for accommodating the volume changes encountered during cycling, to induce shorter lithium ion diffusion pathways in the electrode, and to prevent sulfur dissolution during cycling. A high discharge capacity of 545 mAh g was retained after 500 cycles at 1 C, exhibiting excellent stable cycling performance with 98.

Synthesis and Electrochemical Properties of Amorphous Carbon Coated Sn Anode Material for Lithium Ion Batteries and Sodium Ion Batteries.

Sn is one of the promising anode material for lithium-ion and sodium-ion batteries because of Sn has many advantages such as a high theoretical capacity of 994 mAh/g, inexpensive, abundant and nontoxic. However, Sn-based anodes have a critical problem from pulverization of the particles due to large volume change (>300% in lithium-ion battery and 420% in the sodium-ion battery) during alloying/dealloying reaction. To overcome this problem, we fabricate Sn/C particle of core/shell structure.

Electrochemical Behavior of Sn/CuSn/C Composite Prepared by Using Pulsed Wire Explosion in Liquid Medium for Lithium-Ion Batteries.

Tin-based materials, due to their high theoretical capacity of 994 mAh g-1 are potential candidates which can substitute the commercialized graphite anodes (372 mAh g-1). However, practical usage of pure tin in Li-ion cells has been hampered by the tremendous volume expansion of more than 260% during the lithium insertion/extraction process, resulting in particle pulverization and electrical disconnection from the current collector. In order to overcome this shortcoming, Sn/Cu6Sn5/C composites in this work were prepared by using pulsed wire explosion in a liquid medium and subsequently in situ polymerization.

Electrochemical Properties of Micron-Sized SnO Anode Using a Glyme-Based Electrolyte for Sodium-Ion Battery.

Tin monoxide (SnO) anodes are promising candidates for use in sodium-ion batteries because of their high theoretical capacities and stable cycle performance. In previous reports, electrodes with excellent performance have been prepared by using nano-sized SnO particles. However, the synthesis of nano-sized SnO particles is complex, time-consuming, and expensive.

Carbon-Coated Ordered Mesoporous SnO₂ Composite Based Anode Material for High Performance Lithium-Ion Batteries.

Recently, tin oxide (SnO2) has received significant attention for use as an anode material for next generation lithium-ion batteries (LIBs) owing to its high theoretical capacity (782 mAh g-1), which is more than twice of that of the commercialized graphite (372 mAh g-1). Several additional advantages, such as low cost, environmental friendliness, easy fabrication and natural abundance improve its promise. Although the theoretical capacity of SnO2 is high, volume expansion during cycling causes issue with cycling stability.

Microstructural Evolution and Electrochemical Properties of HRDSR AZ61- ( = Ca, Ti) Alloys.

The microstructure and corrosion properties of as-cast AZ61 (Mg-6%Al-1%Zn) and AZ61 alloys doped with titanium and calcium and subjected to high ratio differential speed rolling were investigated. Addition of the alloying elements to the AZ61 alloy resulted in remarkable modification of the morphology and the amount of continuous β (Mg17Al12)-phase. Addition of Ti to the as-cast AZ61 alloy causes a decrease in the volume fraction (or discontinuity of the β-phase), leading to strong anodic dissolution.

Nitrogen-Doped Mesoporous Carbon: A Top-Down Strategy to Promote Sulfur Immobilization for Lithium-Sulfur Batteries.

The loss of active sulfur material is a challenge in the application of lithium-sulfur (Li-S) batteries. To immobilize sulfur, a nitrogen-doped mesoporous carbon (PMC) was synthesized with polyaniline (PANi) as the carbon source, which was used for development of Li-S batteries. The nitrogen content and pore system of the PMCs were modulated by varying the pyrolysis temperature to impart good electrochemical properties to the Li-S cells.

Co-Ni alloy nanowires prepared by anodic aluminum oxide template via electrochemical deposition.

The alloy nanowires are more prospective magnetic and shape memory materials. Fabrication of binary or more alloy nanowires using electrochemical deposition process is generally challenging due to the different synthesis conditions of individual elements. In the present work, binary NiCo alloy nanowire arrays have been fabricated by electrochemical deposition using anodic aluminum oxide template medium technique.

Electrical and mechanical properties as a processing condition in polyvinylchloride multi walled carbon nanotube composites.

We investigated the electrical conductivity (sigma) and mechanical property of polyvinylchloride/carbon nanotube composites as a function of the CNT content and processing time during a solid-state process of high speed vibration mixing (HSVM) and high energy ball milling (HEBM). Both processes were suggested to avoid high temperatures, solvents, chemical modification of carbon nanotubes. In this study, the percolation threshold (phi(c)) for electrical conduction is about 1 wt% CNT with a sigma value of 0.

High performance enzyme fuel cells using a genetically expressed FAD-dependent glucose dehydrogenase α-subunit of Burkholderia cepacia immobilized in a carbon nanotube electrode for low glucose conditions.

FAD-dependent glucose dehydrogenase (FAD-GDH) of Burkholderia cepacia was successfully expressed in Escherichia coli and subsequently purified in order to use it as an anode catalyst for enzyme fuel cells. The purified enzyme has a low Km value (high affinity) towards glucose, which is 463.8 μM, up to 2-fold exponential range lower compared to glucose oxidase.

Effect of precursor supply on structural and morphological characteristics of fe nanomaterials synthesized via chemical vapor condensation method.

Various physical, chemical and mechanical methods, such as inert gas condensation, chemical vapor condensation, sol-gel, pulsed wire evaporation, evaporation technique, and mechanical alloying, have been used to synthesize nanoparticles. Among them, chemical vapor condensation (CVC) has the benefit of its applicability to almost all materials because a wide range of precursors are available for large-scale production with a non-agglomerated state. In this work, Fe nanoparticles and nanowires were synthesized by chemical vapor condensation method using iron pentacarbonyl (Fe(CO)5) as the precursor.

Physical and electrochemical properties of synthesized carbon nanotubes [CNTs] on a metal substrate by thermal chemical vapor deposition.

Multi-walled carbon nanotubes were synthesized on a Ni/Au/Ti substrate using a thermal chemical vapor deposition process. A Ni layer was used as a catalyst, and an Au layer was applied as a barrier in order to prevent diffusion between Ni and Ti within the substrate during the growth of carbon nanotubes. The results showed that vertically aligned multi-walled carbon nanotubes could be uniformly grown on the Ti substrate (i.