With the increasing importance of decarbonization to prevent global climate change, hydrogen supply has received considerable attention from several countries, including Korea and Japan, due to the growing demand for the implementation of a hydrogen economy. This study conducted a comprehensive analysis on hydrogen supply methods from Australia to the Republic of Korea in environmental and economic aspects using a life cycle assessment (LCA). The blue hydrogen produced in Australia was considered for import to the Republic of Korea via ocean shipping.
View Article and Find Full Text PDFEven though manganese oxides are attractive materials for batteries, super-capacitors and electro-catalysts for oxygen reduction reactions, in most practical applications MnO needs to be hybridized with conductive carbon nano-structures to overcome its inherent poor electrical conductivity. In this manuscript we report microwave-assisted synthesis of MnO embedded carbon nanotubes (MnO@CNT) from Mn-HBTC (benzene-1,3,5-carboxylic acid) metal organic frameworks (MOF) precursors. Using graphene oxide as microwave susceptible surface, MnO nano-particles embedded in three dimensional reduced graphene oxide (rGO) -CNT frameworks (MnO@CNT-rGO) were synthesized which when applied as electro-catalysts in oxygen reduction reaction (ORR) demonstrated comparable half-wave potential to commercial Pt/C, better stability, and excellent immunity to methanol crossover effect in alkaline media.
View Article and Find Full Text PDFNitrogen doped carbon nanotubes (NCNT) that were prepared by simple microwave pyrolysis of Niacin (Vitamin B) as noble metal free electrocatalyst for oxygen reduction reaction (ORR) is reported. Our newly developed technique has the distinct features of sustainable and widely available niacin as a bi-functional source of both carbon and nitrogen, whereas the iron catalyst is cheap and the fourth most common element in the Earth's crust. The results of the electrochemical tests show that our newly developed iron impregnated NCNT anchored on reduced graphene substrate (Fe@NCNT-rGO) catalyst exhibit: a positive half-wave potential (E) of 0.
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