Poly(lactic acid) (PLA) is a relatively brittle polymer, and its low melt strength, ductility, and thermal stability limit its use in various industrial applications. This study aimed to investigate the effect of poly(methyl methacrylate) (PMMA) and PMMA/silica hybrid particles on the mechanical properties, interfacial adhesion, and crystallization behavior of PLA/block acrylic elastomer. PLA/block acrylic elastomer blends exhibit improved flexibility; however, phase separation occurs between PLA and block acrylic elastomer domains.
View Article and Find Full Text PDFThe extreme elasticity and reversible deformability of rubber, which is one of the most versatile polymers in modern society, is dependent on several factors, including the processing conditions, curing system, and types of additives used. Since the rubber's mechanical properties are influenced by the existing structural crosslinks, their correlation with the crosslink characteristics of rubber was investigated using the equilibrium swelling theory of the Flory-Rehner equation and the rubber-filler interaction theory of the Kraus equation. Herein, we examined whether the accelerator and reinforcement agent quantitatively contributed to chemical cross-linkages and rubber-filler interaction.
View Article and Find Full Text PDFThe mechanical properties and tear resistance of an ecofriendly flexible packaging film, i.e., poly(lactic acid) (PLA)/poly (butylene adipate--terephthalate) (PBAT) film, were investigated via a blown film extrusion process.
View Article and Find Full Text PDFPolypropylene (PP) foam offers superior thermal and mechanical properties and versatile applications. However, the linear structure of PP hinders the fabrication of a uniform and fine foam, owing to changes in the melt strength with variations in the temperature. The foamability of the material can be improved by fabricating modified PP by introducing long-chain branches by grafting and chain extension reactions, using glycidyl methacrylate (GMA) and adipic acid (AA).
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