High activity nitrogen and sulfur co-doping high specific surface-modified peanut shell carbon PBC-NS was prepared through one-step carbonization using thiourea and phosphoric acid as modifiers. The TC/Cu(Ⅱ) adsorption characteristics of peanut shell carbon in single and mixed-adsorption systems were discussed, and the enhancement effect and mechanism of modification on TC/Cu(Ⅱ) adsorption were studied. The results showed that the modified peanut shell carbon PBC-NS successfully introduced nitrogen-sulfur functional groups such as Pyridinic N, Graphitic N, C- S-C, and -SH, and the modified specific surface area was as high as 1437 m·g, which was 2.
View Article and Find Full Text PDFUsing cotton stalk as biomass raw material and phosphoric acid as a modifier, narrow pore distribution phosphorus-containing cotton stalk biochar (CSP) with a high surface area (1916 m·g) and pore volume (1.3982 mL·g) was prepared through one-step carbonization, and the adsorption characteristics and mechanisms for tetracycline (TC) were investigated. The results showed that the TC adsorption capacity of CSP was up to 669 mg·g, which was 43.
View Article and Find Full Text PDFBagasse mesoporous carbon was prepared by microwave assisted H3 PO4 activation. Amido and imido groups were modified with ethanediamine on the channels' surface of mesoporous carbon through nitric oxidation and amide reaction. The influence of Pb(II) concentration, adsorption time on Pb(II) adsorption on the ethanediamine-modified mesoporous carbon (AC-EDA) was investigated.
View Article and Find Full Text PDFMesoporous activated carbons containing acidic groups were prepared with cotton stalk based fiber as raw materials and H3PO4 as activating agent by one step carbonization method. Effects of impregnation ratio, carbonization temperature and heat preservation time on the yield, elemental composition, oxygen-containing acid functional groups and adsorptive capacity of activated carbon were studied. The adsorption capacity of the prepared activated carbon AC-01 for p-nitroaniline and Pb(II) was studied, and the adsorption mechanism was also suggested according to the equilibrium experimental results.
View Article and Find Full Text PDFHigh surface area activated carbons were prepared with Spartina alterniflora and cotton stalk as raw materials and KOH as activating agent. Effects of materials type, impregnation ratio, activation temperature and heat preservation time on the yield, elemental composition and adsorptive capacity of activated carbon were studied. The properties and pore structure of the carbons were characterized with nitrogen adsorption, powder X-ray diffractometry (XRD), infrared spectroscopy (FTIR) and scanning electron microscopy (SEM).
View Article and Find Full Text PDFThe two-component serine protease of flaviviruses such as Dengue virus (DENV) and West Nile virus (WNV) are attractive targets for inhibitor/therapeutic design. Peptide aldehyde inhibitors that bind to the covalently tethered two-component WNV protease (WNVpro) with 50% inhibitory concentration (IC(50)) at sub-micromolar concentrations, bind the equivalent DENV-2 protease (DEN2pro) with IC(50) of micromolar concentrations at best. Conversely, the protease inhibitor aprotinin binds DEN2pro ∼1000-fold more tightly than WNVpro.
View Article and Find Full Text PDFLow-cost and high surface area microporous activated carbons were prepared from Spartina alternilora and cotton stalk with KOH activation under the conditions of impregnation ratio of 3.0, activation temperature at 800 degrees C and activation time of 1.5 h.
View Article and Find Full Text PDFLow-cost high surface area microporous carbons were prepared from cotton stalk and cotton stalk fiber by H3PO4 activation. The adsorption of lead ions on the carbons was investigated by conducting a series of batch adsorption experiments. The influence of solution pH value, contact time and temperature was investigated.
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