Facile fabrication of amorphous Al/Fe based metal-organic framework as effective heterogeneous fenton catalyst for environmental remediation.

This study presents a facile preparation and durable amorphous Fe and Al-based MOF nanoplate (AlFe-BTC MOFs) catalyst with notable stability in Fenton reactions. Rigorous characterization using XRD, HR-TEM, and BET confirms the amorphous nature of the synthesized AlFe-BTC MOFs, revealing mesopores (3.4 nm diameter), a substantial surface area (232 m/g), and a pore volume of 0.

Step-Economical Mechanosynthesis of Hybrid Azoles: Deciphering Their π-Orbital and Pharmacological Characteristics.

A hybrid pharmacophore strategy for unifying 1,2,3-triazole with 1,2,4-triazole cores to prepare mixed triazoles was accomplished by a ball-milling approach. The developed chemistry works under the catalysis of cupric oxide nanoparticles with salient features like one-jar operation, lower number of synthetic steps, catalyst recyclability, time-dependent product control, and good overall yields. π-Orbital properties based on theoretical calculations supported the suitability of these molecules for pharmacological screening.