J Colloid Interface Sci
September 2022
Hypothesis: Thermal Marangoni flow in evaporating sessile water droplets is much weaker in experiments than predicted theoretically. Often this is attributed to surfactant contamination, but there have not been any in-depth analyses that consider the full fluid and surfactant dynamics. It is expected that more insight into this problem can be gained by using numerical models to analyze the interplay between thermal Marangoni flow and surfactant dynamics in terms of dimensionless parameters.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2021
Hypothesis: Droplets can absorb into permeable substrates due to capillarity. It is hypothesized that the contact line dynamics influence this process and that an unpinned contact line results in slower absorption than a pinned contact line, since the contact area between the droplet and the substrate will decrease over time for the former. Furthermore, it is expected that surfactants can be used to accelerate the absorption.
View Article and Find Full Text PDFTurbulent mixing is studied in the Lagrangian framework with an approach based on the complex network formalism. We consider the motion of passive, noninertial particles inside a turbulent channel simulated at Re_{τ}=950. The time-dependent network is built to evaluate the transfer of tracers between thin wall-parallel layers which partition the channel in the wall-normal direction.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2021
Hypothesis: Soluble surfactants in evaporating sessile droplets can cause a circulatory Marangoni flow. However, it is not straightforward to predict for what cases this vortical flow arises. It is hypothesized that the occurrence of Marangoni circulation can be predicted from the values of a small number of dimensionless parameters.
View Article and Find Full Text PDFJ Colloid Interface Sci
November 2020
Hypothesis: There are two different sharp-interface models for moving contact lines: slip models and precursor film models. While both models predict a mostly constant contact angle during the evaporation of pure droplets, it is expected that they behave differently when surfactants are present, because of the inherent dissimilarities in their respective interface definitions.
Simulations: Both contact line models are numerically implemented using lubrication theory to analyze evaporating droplets.
A network-based analysis of a turbulent channel flow numerically solved at Re_{τ}=180 is proposed as an innovative perspective for the spatial characterization of the flow field. Two spatial networks corresponding to the streamwise and wall-normal velocity components are built, where nodes represent portions of volume of the physical domain. For each network, links are active if the correlation coefficient of the corresponding velocity component between pairs of nodes is sufficiently high, thus unveiling the strongest kinematic relations.
View Article and Find Full Text PDFWe extended a mathematical model for the drying of sessile droplets, based on the lubrication approximation, to binary mixture droplets. This extension is relevant for e.g.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
August 2016
Evaporating liquid droplets are omnipresent in nature and technology, such as in inkjet printing, coating, deposition of materials, medical diagnostics, agriculture, the food industry, cosmetics, or spills of liquids. Whereas the evaporation of pure liquids, liquids with dispersed particles, or even liquid mixtures has intensively been studied over the past two decades, the evaporation of ternary mixtures of liquids with different volatilities and mutual solubilities has not yet been explored. Here we show that the evaporation of such ternary mixtures can trigger a phase transition and the nucleation of microdroplets of one of the components of the mixture.
View Article and Find Full Text PDFJ Colloid Interface Sci
February 2013
In this paper we study the behavior of an inkjet-printed droplet of a solute dissolved in a solvent on a solid horizontal surface by numerical simulation. An extended model for drying of a droplet and the final distribution of the solute on an impermeable substrate is proposed. The model extends the work by Deegan, Fischer and Kuerten by taking into account convection, diffusion and adsorption of the solute in order to describe more accurately the surface coverage on the substrate.
View Article and Find Full Text PDFA theory was developed that explains energy separation in a vortex tube, known as one of the Maxwellian demons. It appears that there is a unique relation between the pressures in the exits of the vortex tube and its temperatures. Experimental results show that the computed and measured temperatures are in very good agreement.
View Article and Find Full Text PDFThis article presents a numerical model that was developed for the drying of ink-jet-printed polymer solutions after filling the pixels in a polymer LED display. The model extends earlier work presented in the literature while still maintaining a practical approach in limiting the number of input parameters needed. Despite some rigorous assumptions, the model is in fair agreement with experimental data from a pre-pilot ink-jet printing line.
View Article and Find Full Text PDFPhys Rev B Condens Matter
September 1985