Exploiting Online Spatially Resolved Dynamic Light Scattering and Flow-NMR for Automated Size Targeting of PISA-Synthesized Block Copolymer Nanoparticles.

Programmable synthesis of polymer nanoparticles prepared by polymerization-induced self-assembly (PISA) mediated by reversible addition-fragmentation chain-transfer (RAFT) dispersion polymerization with specified diameter is achieved in an automated flow-reactor platform. Real-time particle size and monomer conversion is obtained via inline spatially resolved dynamic light scattering (SRDLS) and benchtop nuclear magnetic resonance (NMR) instrumentation. An initial training experiment generated a relationship between copolymer block length and particle size for the synthesis of poly(,-dimethylacrylamide)--poly(diacetone acrylamide) (PDMAm--PDAAm) nanoparticles.

Organic pollutants in deep sea: Occurrence, fate, and ecological implications.

The deep sea - an oceanic layer below 200 m depths - has important global biogeochemical and nutrient cycling functions. It also receives organic pollutants from anthropogenic sources, which threatens the ecological function of the deep sea. In this Review, critically examined data on the distribution of organic pollutants in the deep sea to outline the role of biogeochemical and geophysical factors on the global distribution and regional chemodynamics of organic pollutants in the deep sea.

Adsorption of sugarcane vinasse effluent on bagasse fly ash: A parametric and kinetic study.

Sugarcane and bioethanol production produces large amounts of bagasse fly ash and vinasse, which are solid and viscous liquid wastes, respectively. However, these wastes are often disposed into the environment without treatment, thus posing an environmental and public health risk. This study investigated the treatment of vinasse effluent in terms of reduction of chemical oxygen demand (COD) and acidity removal using sugarcane bagasse fly ash.