Nanocomposite Membranes Based on Fluoropolymers for Electrochemical Energy Sources.

The physicochemical and transport properties (ion-exchange capacity, water content, diffusion permeability, conductivity, and current-voltage characteristic) of a series of perfluorinated membranes with an inert fluoropolymer content from 0 to 40%, obtained by polymer solution casting, were studied. Based on the analysis of the parameters of the extended three-wire model, the effect of an inert component on the path of electric current flow in the membrane and its selectivity were estimated. The mechanical characteristics of the membranes, such as Young's modulus, yield strength, tensile strength, and relative elongation, were determined from the dynamometric curves.