Chasing equilibrium passive sampling of hydrophobic organic compounds in water.

We investigated a combination of approaches to extend the attainment of partition equilibria between silicone passive samplers (samplers) and surface or treated waste water towards more hydrophobic organic compounds (HOC). The aim was to identify the HOC hydrophobicity range for which silicone sampler equilibration in water is feasible within a reasonable sampler deployment period. Equilibrium partitioning of HOC between sampler and water is desirable for a simpler application as a "chemometer", aiming to compare chemical activity gradients across environmental media (e.

Hexabromocyclododecane: concentrations and isomer profiles from sources to environmental sinks.

Concentrations and isomer compositions of hexabromocyclododecane (HBCD) were measured in six matrices in the Czech Republic (HBCD technical mixture; consumer products; indoor and outdoor air at industrial, urban and background locations; soils; and sediments) to provide insight into changes in concentrations and isomer profiles between environmental sources and environmental sinks. A distinct gradient of air concentrations was observed, from 1600 ng/m in the industrial area to < 10 pg/m in urban and background air. Isomer profiles also showed a distinct gradient in air, from 95% γ-HBCD in industrial air to 40% γ-HBCD in background air, suggesting the influence of differential atmospheric transport and phototransformation of γ- to α-HBCD.

Mobile dynamic passive sampling of trace organic compounds: Evaluation of sampler performance in the Danube River.

A "dynamic" passive sampling (DPS) device, consisting of an electrically driven large volume water pumping device coupled to a passive sampler exposure cell, was designed to enhance the sampling rate of trace organic compounds. The purpose of enhancing the sampling rate was to achieve sufficient method sensitivity, when the period available for sampling is limited to a few days. Because the uptake principle in the DPS remains the same as for conventionally-deployed passive samplers, free dissolved concentrations can be derived from the compound uptake using available passive sampler calibration parameters.

Effect-based monitoring of the Danube River using mobile passive sampling.

Many aquatic pollutants can be present at low concentrations, but their mixtures can still affect health or behavior of exposed organisms. In this study, toxicological and chemical analyses were combined for spatial contamination profiling using an innovative passive sampling approach. A novel Dynamic Passive Sampler (DPS) was employed as a mobile sampler from a ship cruising along 2130km of the Danube river during the Joint Danube Survey 3 (JDS3).

Particle size distribution of halogenated flame retardants and implications for atmospheric deposition and transport.

This study investigates the distribution of polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCD) and a group of novel flame retardants (NFRs) on atmospheric aerosols. Two high volume cascade impactors were used to collect particulate fractions of ambient air over a one year period at urban and rural sites. The majority of FRs were found on the finest aerosols (<0.