Mysteries of TOPSe revealed: insights into quantum dot nucleation.

We have investigated the reaction mechanism responsible for QD nucleation using optical absorption and nuclear magnetic resonance spectroscopies. For typical II-VI and IV-VI quantum dot (QD) syntheses, pure tertiary phosphine selenide sources (e.g.

Statistical fluctuations of transmission in slow light photonic-crystal waveguides.

We report statistical fluctuations for the transmissions of a series of photonic-crystal waveguides (PhCWs) that are supposedly identical and that only differ because of statistical structural fabrication-induced imperfections. For practical PhCW lengths offering tolerable -3dB attenuation with moderate group indices (n(g) approximately 60), the transmission spectra contains very narrow peaks (Q approximately 20,000) that vary from one waveguide to another. The physical origin of the peaks is explained by calculating the actual electromagnetic-field pattern inside the waveguide.

Optical signal processing on a silicon chip at 640Gb/s using slow-light.

We demonstrate optical performance monitoring of in-band optical signal to noise ratio (OSNR) and residual dispersion, at bit rates of 40Gb/s, 160Gb/s and 640Gb/s, using slow-light enhanced optical third harmonic generation (THG) in a compact (80microm) dispersion engineered 2D silicon photonic crystal waveguide. We show that there is no intrinsic degradation in the enhancement of the signal processing at 640Gb/s relative to that at 40Gb/s, and that this device should operate well above 1Tb/s. This work represents a record 16-fold increase in processing speed for a silicon device, and opens the door for slow light to play a key role in ultra-high bandwidth telecommunications systems.

Multiple exciton generation in single-walled carbon nanotubes.

Upon absorption of single photons, multiple excitons were generated and detected in semiconducting single-walled carbon nanotubes (SWNTs) using transient absorption spectroscopy. For (6,5) SWNTs, absorption of single photons with energies corresponding to three times the SWNT energy gap results in an exciton generation efficiency of 130% per photon. Our results suggest that the multiple exciton generation threshold in SWNTs can be close to the limit defined by energy conservation.

Investigation of phase matching for third-harmonic generation in silicon slow light photonic crystal waveguides using Fourier optics.

Using Fourier optics, we retrieve the wavevector dependence of the third-harmonic (green) light generated in a slow light silicon photonic crystal waveguide. We show that quasi-phase matching between the third-harmonic signal and the fundamental mode is provided in this geometry by coupling to the continuum of radiation modes above the light line. This process sustains third-harmonic generation with a relatively high efficiency and a substantial bandwidth limited only by the slow light window of the fundamental mode.

Optical chromatography using a photonic crystal fiber with on-chip fluorescence excitation.

We describe the realization of integrated optical chromatography, in conjunction with on-chip fluorescence excitation, in a monolithically fabricated poly-dimethylsiloxane (PDMS) microfluidic chip. The unique endlessly-single-mode guiding property of the Photonic Crystal Fiber (PCF) facilitates simultaneous on-chip delivery of beams to perform optical sorting in conjunction with fluorescence excitation. We use soft lithography to define the chip and insert the specially capped PCF into it through a predefined fiber channel that is intrinsically aligned with the sorting channel.

Nonlinear loss dynamics in a silicon slow-light photonic crystal waveguide.

We directly investigate both experimentally and numerically the influence of optical nonlinear loss dynamics on a silicon waveguide based all-optical device. The dynamics of these nonlinear losses are explored through the analysis of optical limiting of an amplitude distorted 10 Gbit/s signal in a slow-light silicon photonic crystal waveguide. As the frequency of the distortion approaches the free-carrier recombination rate, free-carrier absorption reaches a steady state, leaving two-photon absorption the dominant dynamic nonlinear loss.

Assessing the depth of hypnosis of xenon anaesthesia with the EEG.

Xenon was approved as an inhaled anaesthetic in Germany in 2005 and in other countries of the European Union in 2007. Owing to its low blood/gas partition coefficient, xenons effects on the central nervous system show a fast onset and offset and, even after long xenon anaesthetics, the wake-up times are very short. The aim of this study was to examine which electroencephalogram (EEG) stages are reached during xenon application and whether these stages can be identified by an automatic EEG classification.

Zinc porphyrin as a donor for FRET in Zn(II)cytochrome c.

We demonstrate that Zn(II) porphyrin in Zn(II)cytochrome c (Zn cyt c) is a fluorescence resonance energy transfer (FRET) donor to an Alexa660 dye acceptor. The energy transfer efficiency is dependent on the distance between the two fluorophores as shown through protein denaturation studies of five Zn cyt c variants labeled with Alexa660 in different positions. The relative quantum yield, excitation and emission energies, and labeling efficiencies of this donor-acceptor pair allow for a method of analysis based on sensitized emission of the acceptor.

High-speed modulation of a compact silicon ring resonator based on a reverse-biased pn diode.

High speed modulation based on a compact silicon ring resonator operating in depletion mode is demonstrated. The device exhibits an electrical small signal bandwidth of 19 GHz. The device is therefore a candidate for highly compact, wide bandwidth modulators for a variety of applications.

Complete response characterization of ultrafast linear photonic devices.

We present a method to fully characterize linear photonic devices that change their properties on ultrashort time scales. When we feed the device with a broadband input pulse and detect the resulting output field for a sufficient number of arrival times of the input, the device response to any other input with smaller bandwidth can be extracted numerically, without the need for additional measurements. Our approach is based on the formalism of linear time-varying systems, and we experimentally demonstrate its feasibility for the example of an ultrafast nanophotonic switch.

Optical filter with very large stopband (approximately 300 nm) based on a photonic-crystal vertical-directional coupler.

We have designed, fabricated, and demonstrated a vertical directional coupler based on the coupling between a polymer waveguide and a W1 photonic crystal waveguide. The filters have a bandwidth of approximately 2 nm within a stopband of Delta lambda approximately 300 nm and an on-chip insertion loss of 1 dB. This is the first (to our knowledge) demonstration of a filter with such a large stopband that overcomes the bandwidth limitation of existing filters.

Hybrid-repair of thoraco-abdominal or juxtarenal aortic aneurysm: what the radiologist should know.

Purpose: Endovascular aneurysm repair of the infrarenal or thoracic aorta has been shown to be a less invasive alternative to open surgery. A combined aneurysm of the thoracic and abdominal aorta is complex and challenging; the involvement of renal and/or visceral branches requires new treatment methods.

Methods: A hybrid approach is currently an accepted alternative to conventional surgery.

Supramolecular assembly of a 2D binary network of pentacene and phthalocyanine on Cu(100).

A crystalline nanoporous molecular network was tailored by supramolecular assembly of pentacene and F16CuPc on Cu(100). The structure and self-assembly mechanisms of the pure and binary layers were analyzed by STM. F16CuPc films and mixed layers of pentacene/F16CuPc in a ratio of 2:1 show two enantiomorphic chiral domains with high structural order in contrast to pentacene which exhibits no long-range order in pure films.

Label-free DNA detection on nanostructured Ag surfaces.

The dramatic local electric-field enhancement property of Ag nanoparticles was used as the basis to significantly increase the signal output of a novel label-free (or "self-labeled") fluorescence-based DNA detection system. In response to identical amounts of analyte, nanostructured Ag substrates provided a posthybridization fluorescent sensor response over 10-fold larger than the response from planar Au substrates. Detection performance strongly depended upon the Ag substrate roughness.

Non-blinking semiconductor nanocrystals.

The photoluminescence from a variety of individual molecules and nanometre-sized crystallites is defined by large intensity fluctuations, known as 'blinking', whereby their photoluminescence turns 'on' and 'off' intermittently, even under continuous photoexcitation. For semiconductor nanocrystals, it was originally proposed that these 'off' periods corresponded to a nanocrystal with an extra charge. A charged nanocrystal could have its photoluminescence temporarily quenched owing to the high efficiency of non-radiative (for example, Auger) recombination processes between the extra charge and a subsequently excited electron-hole pair; photoluminescence would resume only after the nanocrystal becomes neutralized again.

Women need more propofol than men during EEG-monitored total intravenous anaesthesia / Frauen benötigen mehr Propofol als Männer während EEG-überwachter total-intravenöser Anästhesie.

Gender-related differences in the pharmacology of drugs used in anaesthesiology have been reported by different authors. The aim of this study was to compare propofol dosages in a greater number of male and female patients who had received electroencephalogram (EEG) monitoring to maintain a defined depth of anaesthesia. Data from an EEG-controlled study were analysed with regard to gender differences in the consumption of the short-acting hypnotic propofol during maintenance of total intravenous anaesthesia and with regard to recovery times.

Gender effects on novel time domain parameters of ventricular repolarization inhomogeneity.

Introduction: Parameters of ventricular repolarization variability are increasingly being used in an attempt to understand better and predict the occurrence of ventricular tachycardia. Nevertheless, some of the measures used have thus far not been analyzed regarding gender differences in a large group of healthy subjects. Furthermore, new parameters might give further insight.

Integrated polymer microprisms for free space optical beam deflecting.

We demonstrate beam deflection and multiple channel communication in free space optical communications using microprisms integrated directly onto an array of vertical cavity surface emitting lasers (VCSELs). The design and fabrication of such a transmitter is presented, and shown to achieve beam deflection of up to 10 degrees in a planar configuration. A location discovery application, for use within a distributed network, is put forward and analysed.

Slow light enhancement of nonlinear effects in silicon engineered photonic crystal waveguides.

We report nonlinear measurements on 80microm silicon photonic crystal waveguides that are designed to support dispersionless slow light with group velocities between c/20 and c/50. By launching picoseconds pulses into the waveguides and comparing their output spectral signatures, we show how self phase modulation induced spectral broadening is enhanced due to slow light. Comparison of the measurements and numerical simulations of the pulse propagation elucidates the contribution of the various effects that determine the output pulse shape and the waveguide transfer function.

[Management of hypertension (ESC Guideline 2007/DHL Guideline 2008)].

The 2007 ESH/ESC (European Society of Hypertension/European Society of Cardiology) guidelines for the management of arterial hypertension focus on the individual patient with his specific cardiovascular risk profile. The existing hypertension classification remains the same as in previous editions. However, specific patient characteristics and risk profiles require a more individualized approach.

Small-angle rotation in individual colloidal CdSe quantum rods.

CdSe quantum rods (QRs) are very promising novel materials with unique electronic and optical properties. In this paper, we utilize a broad spectrum of techniques including high-resolution annular dark field scanning transmission electron microscope imaging, electron nanodiffraction, and computer simulations to study the internal structure of individual QRs. Random small-angle rotations are commonly found between various sections within individual QRs which can be resolved into twists around the c-axis and bends.