Excitonic Effects in Energy-Loss Spectra of Freestanding Graphene.

In this work, we perform electron energy-loss spectroscopy (EELS) of freestanding graphene with high energy and momentum resolution to disentangle the quasielastic scattering from the excitation gap of Dirac electrons close to the optical limit. We show the importance of many-body effects on electronic excitations at finite transferred momentum by comparing measured EELS to ab initio calculations at increasing levels of theory. Quasi-particle corrections and excitonic effects are addressed within the GW approximation and the Bethe-Salpeter equation, respectively.

Progress in Carbon Nanostructures: From Synthesis to Applications.

Significant progress in carbon nanostructures has been achieved in the past 20 years; however, there is plenty of room for further study [...

Cytotoxicity of Carbon Nanotubes, Graphene, Fullerenes, and Dots.

The cytotoxicity of carbon nanomaterials is a very important issue for microorganisms, animals, and humans. Here, we discuss the issues of cytotoxicity of carbon nanomaterials, carbon nanotubes, graphene, fullerene, and dots. Cytotoxicity issues, such as cell viability and drug release, are considered.

Advanced Carbon Nanostructures: Synthesis, Properties, and Applications.

Carbon nanomaterials are a class of materials that include allotropic modifications of carbon [...

Metallocene-Filled Single-Walled Carbon Nanotube Hybrids.

In this paper, the growth mechanism, structure, growth processes, growth kinetics, and optical, vibronic and electronic properties of metallocene-filled single-walled carbon nanotubes (SWCNTs) are considered. A description of the procedures used to fill the nanotubes is provided. An investigation of doping effects on metallicity-mixed SWCNTs filled with metallocenes by Raman spectroscopy, near edge X-ray absorption fine structure spectroscopy, photoemission spectroscopy, and optical absorption spectroscopy is described.

Electrochemistry of Carbon Materials: Progress in Raman Spectroscopy, Optical Absorption Spectroscopy, and Applications.

This paper is dedicated to the discussion of applications of carbon material in electrochemistry. The paper starts with a general discussion on electrochemical doping. Then, investigations by spectroelectrochemistry are discussed.

Functionalized Fullerenes and Their Applications in Electrochemistry, Solar Cells, and Nanoelectronics.

Carbon-based nanomaterials have rapidly advanced over the last few decades. Fullerenes, carbon nanotubes, graphene and its derivatives, graphene oxide, nanodiamonds, and carbon-based quantum dots have been developed and intensively studied. Among them, fullerenes have attracted increasing research attention due to their unique chemical and physical properties, which have great potential in a wide range of applications.

Phemenology of Filling, Investigation of Growth Kinetics and Electronic Properties for Applications of Filled Single-Walled Carbon Nanotubes.

This review discusses the phemenology of filling, the investigation of kinetics, and the electronic properties for applications of filled single-walled carbon nanotubes (SWCNTs), and summarizes five main achievements that were obtained in processing the spectroscopic data of SWCNTs filled with metal halogenide, metal chalcogenide, metal and metallocenes. First, the methods of processing kinetic data were developed to reveal precise trends in growth rates and activation energies of the growth of SWCNTs. Second, the metal-dependence of kinetics was revealed.

Metal and Metal Halogenide-Filled Single-Walled Carbon Nanotubes: Kinetics, Electronic Properties, Engineering the Fermi Level.

Here, we present a review of the major achievements in kinetics, electronic properties, and engineering in the Fermi level of single-walled carbon nanotubes (SWCNTs). Firstly, the kinetics of metal-filled SWCNTs were revealed with precision over several minutes. Secondly, the growth rates of nanotubes were calculated.

Synthesis, Sorting, and Applications of Single-Chirality Single-Walled Carbon Nanotubes.

The synthesis of high-quality chirality-pure single-walled carbon nanotubes (SWCNTs) is vital for their applications. It is of high importance to modernize the synthesis processes to decrease the synthesis temperature and improve the quality and yield of SWCNTs. This review is dedicated to the chirality-selective synthesis, sorting of SWCNTs, and applications of chirality-pure SWCNTs.

Spectroscopy of Filled Single-Walled Carbon Nanotubes.

Many envisaged applications, such as nanoelectronics, photovoltaics, thermoelectric power generation, light-emission devices, energy storage and biomedicine, necessitate single-walled carbon nanotube (SWCNT) samples with specific uniform electronic properties. The precise investigation of the electronic properties of filled SWCNTs on a qualitative and quantitative level is conducted by optical absorption spectroscopy, Raman spectroscopy, photoemission spectroscopy and X-ray absorption spectroscopy. This review is dedicated to the description of the spectroscopic methods for the analysis of the electronic properties of filled SWCNTs.

Applications of Pristine and Functionalized Carbon Nanotubes, Graphene, and Graphene Nanoribbons in Biomedicine.

This review is dedicated to a comprehensive description of the latest achievements in the chemical functionalization routes and applications of carbon nanomaterials (CNMs), such as carbon nanotubes, graphene, and graphene nanoribbons. The review starts from the description of noncovalent and covalent exohedral modification approaches, as well as an endohedral functionalization method. After that, the methods to improve the functionalities of CNMs are highlighted.

Temperature-Dependent Growth of 36 Inner Nanotubes inside Nickelocene, Cobaltocene and Ferrocene-Filled Single-Walled Carbon Nanotubes.

We have investigated the effects of temperature, diameter and metal catalyst type on the growth of inner nanotubes inside metallocene-filled single-walled carbon nanotubes (SWCNTs). The effects on the yield of different chiralities of inner nanotubes were scrutinized by multifrequency Raman spectroscopy. The investigated diameters range from ~0.

Applications of Filled Single-Walled Carbon Nanotubes: Progress, Challenges, and Perspectives.

Single-walled carbon nanotubes (SWCNTs), which possess electrical and thermal conductivity, mechanical strength, and flexibility, and are ultra-light weight, are an outstanding material for applications in nanoelectronics, photovoltaics, thermoelectric power generation, light emission, electrochemical energy storage, catalysis, sensors, spintronics, magnetic recording, and biomedicine. Applications of SWCNTs require nanotube samples with precisely controlled and customized electronic properties. The filling of SWCNTs is a promising approach in the fine-tuning of their electronic properties because a large variety of substances with appropriate physical and chemical properties can be introduced inside SWCNTs.

Metal Cluster Size-Dependent Activation Energies of Growth of Single-Chirality Single-Walled Carbon Nanotubes inside Metallocene-Filled Single-Walled Carbon Nanotubes.

By combining in situ annealing and Raman spectroscopy measurements, the growth dynamics of nine individual-chirality inner tubes (8,8), (12,3), (13,1), (9,6), (10,4), (11,2), (11,1), (9,3) and (9,2) with diameters from ~0.8 to 1.1 nm are monitored using a time resolution of several minutes.

Characterizing the maximum number of layers in chemically exfoliated graphene.

An efficient route to synthesize macroscopic amounts of graphene is highly desired and bulk characterization of such samples, in terms of the number of layers, is equally important. We present a Raman spectroscopy-based method to determine the typical upper limit of the number of graphene layers in chemically exfoliated graphene. We utilize a controlled vapour-phase potassium intercalation technique and identify a lightly doped stage, where the Raman modes of undoped and doped few-layer graphene flakes coexist.

π/2 mode converters and vortex generators for electrons.

In optics, mode conversion is an elegant way to switch between Hermite Gaussian and Laguerre Gaussian beam profiles and thereby impart orbital angular momentum onto the beam and to create vortices. In optics such vortex beams can be produced in a setup consisting of two identical cylinder lenses. In electron optics, quadrupole lenses can be used for the same purpose.

Feedstock-dependent nitrogen configurations of nitrogen-doped single-walled carbon nanotubes in a CVD process.

The modification of nitrogen configurations is a viable way to control the electronic properties of nitrogen-doped single-walled carbon nanotubes (N-doped SWCNTs). N-doped SWCNTs were synthesized by a conventional chemical vapor deposition process with a mixed carbon/nitrogen (C/N) feedstock. While higher feedstock flow rates promote the formation of encapsulated N2 molecules, lower flow rates show a predominance of pyridinic and graphitic nitrogen structures as revealed by X-ray photoemission spectroscopy.

Insights into radiation damage from atomic resolution scanning transmission electron microscopy imaging of mono-layer CuPcCl films on graphene.

Atomically resolved images of monolayer organic crystals have only been obtained with scanning probe methods so far. On the one hand, they are usually prepared on surfaces of bulk materials, which are not accessible by (scanning) transmission electron microscopy. On the other hand, the critical electron dose of a monolayer organic crystal is orders of magnitudes lower than the one for bulk crystals, making (scanning) transmission electron microscopy characterization very challenging.

Software electron counting for low-dose scanning transmission electron microscopy.

The performance of the detector is of key importance for low-dose imaging in transmission electron microscopy, and counting every single electron can be considered as the ultimate goal. In scanning transmission electron microscopy, low-dose imaging can be realized by very fast scanning, however, this also introduces artifacts and a loss of resolution in the scan direction. We have developed a software approach to correct for artifacts introduced by fast scans, making use of a scintillator and photomultiplier response that extends over several pixels.

Chirality-dependent growth of single-wall carbon nanotubes as revealed inside nano-test tubes.

Growth dynamics of single-wall carbon nanotubes (SWCNTs) have been studied with nickelocene as a precursor encapsulated in the interior of template SWCNTs. By means of multi-laser Raman spectroscopy, growth curves of nine different SWCNTs, (8,8), (12,3), (13,1), (9,6), (10,4), (11,2), (11,1), (9,3) and (9,2), have been determined upon in situ annealing at various temperatures. The data reveal that the nanotubes grow through fast and slow reaction pathways with high and low activation energies, respectively.

Automated Image Acquisition for Low-Dose STEM at Atomic Resolution.

Beam damage is a major limitation in electron microscopy that becomes increasingly severe at higher resolution. One possible route to circumvent radiation damage, which forms the basis for single-particle electron microscopy and related techniques, is to distribute the dose over many identical copies of an object. For the acquisition of low-dose data, ideally no dose should be applied to the region of interest before the acquisition of data.

Fingerprinting seamless single-walled carbon nanotube junctions via the migration of encapsulated N molecules from bottom to top: are arrays of VA-SWNTs continuous?

Structure control such as diameter changes along single-walled carbon nanotubes (SWNTs) can be achieved in arrays of vertically aligned (VA-) SWNTs by switching the feedstock during growth. The local nature of the macroscopic transition from one diameter to another is then questioned as one can either envisage seamless transitions or discontinuous individual SWNTs. Here, we demonstrate that encapsulated molecules can serve as markers to doubtlessly identify seamless interconnections in macroscopic samples.

Unraveling the 3D Atomic Structure of a Suspended Graphene/hBN van der Waals Heterostructure.

In this work we demonstrate that a free-standing van der Waals heterostructure, usually regarded as a flat object, can exhibit an intrinsic buckled atomic structure resulting from the interaction between two layers with a small lattice mismatch. We studied a freely suspended membrane of well-aligned graphene on a hexagonal boron nitride (hBN) monolayer by transmission electron microscopy (TEM) and scanning TEM (STEM). We developed a detection method in the STEM that is capable of recording the direction of the scattered electron beam and that is extremely sensitive to the local stacking of atoms.

Progress in structure recovery from low dose exposures: Mixed molecular adsorption, exploitation of symmetry and reconstruction from the minimum signal level.

We investigate the recovery of structures from large-area, low dose exposures that distribute the dose over many identical copies of an object. The reconstruction is done via a maximum likelihood approach that does neither require to identify nor align the individual particles. We also simulate small molecular adsorbates on graphene and demonstrate the retrieval of images with atomic resolution from large area and extremely low dose raw data.