Publications by Kouta Kagimoto

Publications by authors named "Kouta Kagimoto"

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CO insertion in lithiated diene-tricarbonyliron complexes.

Tatsuo Okauchi Takao Teshima Mitsuru Sadoshima Hidekazu Kawakubo Kouta Kagimoto

Chem Commun (Camb)

July 2010

Lithiated 1,3-diene-iron complexes undergo a CO insertion in the presence of trimethyl phosphite via a ferrate intermediate to give 3-formyl or 3-acetyl-1,3-diene-Fe(CO)(2)P(OMe)(3) complexes. Formylation proceeds when the reaction is quenched by a strong Brønsted acid, whereas the ketone is obtained after the treatment with iodomethane.

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