Novel tunneled phosphorus-doped WO films achieved using ignited red phosphorus for stable and fast switching electrochromic performances.

Simultaneous improvement of both the performance and stability of electrochromic devices (ECDs) to encourage their practical use in various applications, such as commercialized smart windows, electronic displays, and adjustable mirrors, by tuning the film structure and the electronic structure of transition metal oxides remains a challenging issue. In the present study, we developed novel tunneled phosphorus (P)-doped WO3 films via the ignition reaction of red P. The ignited red P, which can generate exothermic energy, was used as an attractive factor to create a tunneled structure and P-doping on the WO3 films.

Improvement of Transparent Conducting Performance on Oxygen-Activated Fluorine-Doped Tin Oxide Electrodes Formed by Horizontal Ultrasonic Spray Pyrolysis Deposition.

In this study, highly transparent conducting fluorine-doped tin oxide (FTO) electrodes were fabricated using the horizontal ultrasonic spray pyrolysis deposition. In order to improve their transparent conducting performances, we carried out oxygen activation by adjusting the ratio of O/(O+N) in the carrier gas (0%, 20%, and 50%) used during the deposition process. The oxygen activation on the FTO electrodes accelerated the substitution concentration of F (F) into the oxygen sites in the FTO electrode while the oxygen vacancy (V) concentration was reduced.

Fast-switching electrochromic properties of mesoporous WO films with oxygen vacancy defects.

In this study, mesoporous WO films with oxygen vacancy defects have been fabricated using the camphene-assisted sol-gel method. By controlling the optimized weight ratio of camphene on the WO films, we developed a unique film structure of the WO phase with both mesoporous morphology and oxygen vacancy defects due to the distinctive effect of camphene. The mesoporous WO films with oxygen vacancy defects fabricated using 10 wt% camphene showed superb multifunctional electrochromic (EC) properties with both fast switching speeds (5.

Activated mesoporous carbon nanofibers fabricated using water etching-assisted templating for high-performance electrochemical capacitors.

Activated mesoporous carbon nanofibers (AMCNFs) are synthesized by a sequential process of electrospinning, water etching-assisted templating, and acid treatment. Their morphologies, crystal structures, melting behavior, chemical bonding states, surface properties, and electrochemical performance are investigated for three different polyacrylonitrile (PAN) to polyvinylpyrrolidone (PVP) weight ratios - PAN : PVP = 8 : 2, 7 : 3, and 6 : 4. Compared to other samples, the AMCNFs with an optimum weight ratio of 6 : 4 show the highest specific surface area of 692 m(2) g(-1), a high volume percentage of mesopores of 43.

Surface modification and characterization of electrosprayed Sn-doped In2O3 thin films.

We synthesized Sn-doped In2O3 (Indium tin oxide, ITO) thin films using electrospray and spin-coating. Scanning electron microscopy, atomic force spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Hall-effect measurement, and UV-vis spectrophotometry measurements were performed to investigate the morphological, structural, chemical, electrical, and optical properties of the electrosprayed ITO films with a sol-layer coating for surface modification. To obtain the optimum performance of the resultant ITO thin films after surface modification, we heat-treated them at four different temperatures of 450 degrees C (sample A), 550 degrees C (sample B), 650 degrees C (sample C), and 750 degrees C (sample D) using microwave heating.

Synthesis and characterisation of polygonal indium tin oxide nanocrystals.

Polygon ITO (Sn-doped In2O3) nanocrystals were synthesised via electrospinning, and their morphology, structural properties, and chemical composition were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). To determine the optimum conditions for the fabrication of polygon ITO nanocrystals, calcination temperature after the electrospinning process was controlled at 500 degrees C, 600 degrees C, 700 degrees C, and 800 degrees C, and the amount of PVP polymer was controlled at 4 wt%, 7 wt%, and 10 wt%. For comparison purposes, single In2O3 nanocrystals were also synthesised via electrospinning and calcination.