Charge Me Slowly, I Am in a Hurry: Optimizing Charge-Discharge Cycles in Nanoporous Supercapacitors.

Nanoporous supercapacitors attract much attention as green energy storage devices with remarkable cyclability and high power and energy densities. However, their use in high-frequency applications is limited by relatively slow charging processes, while accelerating charging without compromising the energy storage still remains a challenging task. Here, we study in detail the charging and discharging behavior of nanoporous supercapacitors with narrow pores, which provide exceptionally high capacitances and stored energy densities.

The effect of finite pore length on ion structure and charging.

Nanoporous supercapacitors play an important role in modern energy storage systems, and their modeling is essential to predict and optimize the charging behaviour. Two classes of models have been developed that consist of finite and infinitely long pores. Here, we show that although both types of models predict qualitatively consistent results, there are important differences emerging due to the finite pore length.

Capacitance of Nanoporous Carbon-Based Supercapacitors Is a Trade-Off between the Concentration and the Separability of the Ions.

Nanoporous carbon-based supercapacitors store electricity through adsorption of ions from the electrolyte at the surface of the electrodes. Room temperature ionic liquids, which show the largest ion concentrations among organic liquid electrolytes, should in principle yield larger capacitances. Here, we show by using electrochemical measurements that the capacitance is not significantly affected when switching from a pure ionic liquid to a conventional organic electrolyte using the same ionic species.

Coarse-grained simulations of an ionic liquid-based capacitor: II. Asymmetry in ion shape and charge localization.

In this work, which is a continuation of part I, we introduce a primitive model for an ionic liquid (IL) that can account for the planar shape of cations typical for ILs like imidazolium. The model consists of a spherical anion and a triangular cation consisting of three spheres, where one or all three vertices of the triangle can carry electric charge. We use molecular dynamics simulations to study the differential capacitance Cd of an ionic liquid confined between two planar electrodes.

Coarse-grained simulations of an ionic liquid-based capacitor: I. Density, ion size, and valency effects.

We introduce a hierarchy of generic coarse-grained models of ionic liquids of increasing complexity. We use them in molecular dynamics simulations to study the differential capacitance of a capacitor consisting of an ionic liquid between two planar electrodes. The primary goal is to explain the complex dependence of the differential capacitance Cd on the electrode potential U in simple terms, e.