Publications by authors named "Kolekar G"

The naked-eye detection of hazardous pollutants through simple and cost-effective techniques is of great interest to the scientific community and related stakeholders in analytical science. The present study emphases the development of a stimuli-responsive probe by encountering sophisticated techniques for the detection of environmental pollutants. Herein, highly swellable and fluorescent-WTR-CDs-loaded HB-Alg/Gel@WTR-CDs was fabricated through a simple extrusion dripping method.

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In this study, we investigate, for the first time, the abundance, distribution, chemical composition, and exposure of microplastics (MPs) in Indian rice and their impact on human health. The physical and chemical characteristics of MPs were measured using a stereomicroscope, μ-Fourier transform infrared spectroscopy, and μ-Raman spectroscopy. MPs were identified in all samples, with an average abundance of 30.

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Around 1.5 million mortality cases due to fungal infection are reported annually, posing a massive threat to global health. However, the effectiveness of current antifungal therapies in the treatment of invasive fungal infections is limited.

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The present study explores the kitchen waste okra peels derived synthesis of nitrogen doped carbon dots (N-CDs) via simple carbonization followed by reflux method. The synthesized N-CDs was characterized using, TEM, XPS, FTIR, XRD, Raman, UV-Visible and Fluorescence Spectroscopy. The N-CDs emits bright blue emission at 420 nm with 12 % of quantum yield as well as it follows excitation dependent emission.

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Nanocarriers have attracted considerable interest due to their prospective applications in the delivery of anticancer medications and their distinct bioactivities. Biogenic nanostructures can be effective nanocarriers for delivering drugs as a consequence of sustainable and biodegradable biomass-derived nanostructures that perform specific functions. In this case, a vanadium oxide (VO) and mesoporous carbon@VO (C@V) composite was developed as a possible drug delivery system, and its bioactivities, including antioxidant, antibacterial, and anticancer, were investigated.

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()-Ethyl 2-cyano-3-(4'-(diphenyl amino)-[1,1'-biphenyl]-4-yl) acrylate (RSJ) is a novel luminogen based on triphenylamine. It has been fully synthesized and characterized, exhibiting an incredible photophysical phenomenon known as aggregation-induced emission (AIE). This work describes a fluorescent sensor that detects vitamin B2 in mixed aqueous media with high selectivity and a low limit of detection as well as a mechanism for reversible mechanochromic luminescence.

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In this work, we used a one-step hydrothermal method to synthesize blue-emission sulfur-doped carbon dots (S-CDs) using jaggery as a carbon precursor. The synthesized carbon quantum dots showed low toxicity, good water solubility, anti-interference properties, and stable fluorescence. When excited at 310 nm, the S-CDs produced bright emission with a quantum yield of 7.

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The present investigation explores the different pathways for development of waste tea residue carbon dots (WTR-CDs) loading into hydrogel matrix for WTR-CDs releasing probe. Fluorescent WTR-CDs incorporated into hydrogel matrix were synthesized by valorisation of kitchen waste tea by simple carbonization method (λ = 450 nm, Φ =18.45 %).

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Carbon dots have demonstrated a great potential as luminescent nanoparticles in energy, drug delivery, sensors, and various biomedical applications as well as environmental pollutants and water analysis. Although, such nanoparticles appear to exhibit low toxicity compared to other semiconductor and metal based luminescent nanomaterials. Today, we know that toxicity of carbon dots (CDs) strongly depends on the protocol of fabrication.

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A newly synthesized AIEgen based on triphenylamine is fully characterized and coded as BRA for the simultaneous and discriminatory selective detection of Hg and Ag ions directly in mixed aqueous media for the identification and purification of water with a low detection limit. Moreover, we employed BRA in histotoxicity in that when compared to the control group, fish exposed to the "novel synthesized luminogen (BRA)" that demonstrated photophysical phenomena during the "sensing of mercury and silver (heavy metals) in aqueous media" did not show any major distinguishing changes in the architecture of their gills, liver, muscle, brain, kidney, and heart tissues.

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Sodium dodecyl sulfate (SDS)-capped 1-pyrenecarboxaldehyde nanoparticles (PyalNPs) were prepared using a reprecipitation method in an aqueous medium and exhibited red-shifted aggregation-induced enhanced emission (AIEE). The dynamic light scattering (DLS) examination showed narrower particle size distribution with an average particle size of 41 nm, whereas -34.5 mV zeta potential value indicate the negative surface charge and good stability of nanoparticles (NPs) in an aqueous medium.

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Scientists have investigated the possibility of employing nanomaterials as drug carriers. These nanomaterials can preserve their content and transport it to the target region in the body. In this investigation, we proposed a simple method for developing distinctive, bioderived nanostructures with mesoporous carbon nanoparticles impregnated with tungsten oxide (WO).

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Fluorescent organic nanoparticles (FONPs) have attracted much attention as a practicable and effective platform for detection applications. The present article describes the preparation of FONPs derived from the quinazolinone-based 2-(furan-2-yl)-2,3-dihydroquinazolin-4(1H)-one derivative FHDQ. Self-assembly of FHDQ in an aqueous medium resulted in the formation of FONPs through H-type aggregation and showed excellent fluorescence properties.

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In this article, we present the synthesis of calcium sulfate nanoparticles (CaSO NPs) from waste chalk powder by the calcination method. These CaSO NPs were utilized for the construction of a mesoporous graphitic carbon nitride-calcium sulfate (mpg-CN-CaSO) photocatalyst. Synthesized materials were confirmed by several characterization techniques.

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This study explored a novel, eco-friendly, sustainable, low-cost, and abundantly available corn comb (CC) agricultural biomass waste-derived one-step in-situ synthesis of magnetic carbon (MCCC) as an efficient adsorbent for water decontamination applications. Herein, we developed a robust and easily separable MCCC by carbonization of Fe(NO).9HO single iron salt-soaked CC at 500 °C for 5 h.

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The waste of tungsten filament materials in the environment is one of the reasons for environmental pollution, and it is very dangerous to animals and plants. To date, not much attention has been given to its utility or recyclability. Herein, the present work reported the synthesis of tungsten trioxide nanoparticles (WO NPs) by the utilization of cost-free waste tungsten filament by a simple calcination method.

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It is critical to design a novel and simple bifunctional sensor for the selective and sensitive detection of ions in an aqueous media in environmental samples. As a result, in this study, tetraphenylethene hydrazinecarbothioamide (TPE-PVA), known as probe 1, was successfully synthesized and characterized as having impressive photophysical phenomena such as aggregation-induced emission (AIE) and mechanochromic properties by applying mechanical force to the solid of probe 1. The emission of the solid of probe 1 changed from turquoise blue to lemon yellow after grinding, from lemon yellow to parakeet green after annealing at 160 °C, and to arctic blue after fuming with DCM.

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This study illustrates the synthesis of functionalized carbon quantum dots (CQDs) by the one-pot pyrolysis method. The functionalization agent used in CQD synthesis was poly l- lysine (PLL). Various physicochemical techniques were employed to confirm the successful formation of PLLCQD including High resolution transmission electron microscopy (HR-TEM), UV-Vis spectroscopy, fluorescence spectroscopy; Atomic force microscopy (AFM), X-ray Photoelectron Spectroscopy (XPS) and X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy.

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A simple method for the synthesis of indeno-[1,2-]-quinoline-9,11-(6,10)-dione derivatives and 7,7-dimethyl-10-aryl-7,8-dihydro-5-indeno[1,2-]quinoline-9,11(6,10)-diones through the reaction of aromatic aldehydes, indan-1,3-dione, dimedone, and -toluidine/ammonium acetate in the presence of heterogeneous CuO supported on a zeolite-Y catalyst has been investigated in ethanol under reflux conditions. By this method, the reaction time has been reduced, giving an excellent yield of the product. The catalyst was prepared by a hydrothermal method followed by a wet impregnation method.

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Since their discovery in 2004, fluorescent carbon nanoparticles have been tremendously studied due to their tunable optical properties. Recent studies on the synthesis and application of doped carbon dots highlight the effortless doping strategy with high quantum yields and applications in diverse fields. Among these, nitrogen doped carbon dots (NCDs) have been extensively investigated for their potential analytical and biological applications.

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Fluorescent carbon dots (CDs) are one of the important carbonaceous nanomaterials in the area of nanoscience and nanotechnology because of their interesting physical as well as chemical properties. Herein we studied the effect of various aqueous extracting agents on fluorescence properties of waste tea residue-based carbon dots (WTR-CDs). WTR-CDs are firstly synthesized by utilizing kitchen waste-based carbonaceous biomass.

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Herein, for the first time the carbon dots (CDs) were synthesized by reflux method from sawmill waste material. We also represent a novel strategy based on fluorescent CDs for determination of ponceau 4R and allura red dyes in soft drinks. Interestingly, both the dyes were sensitive and showed effective fluorescence quenching of the CDs owing to the interaction between them.

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Herein, we report the utilization of kitchen waste biomass as a source of carbonaceous material for carbon nanodots synthesis and its application as a plant growth regulator in agricultural crops. The water soluble carbon dots (CDs) were synthesized by pyrolysis of kitchen derived waste tea residue (WTR) and used in the field of agriculture nanotechnology. Herein, we have explored the effect of different concentrations of WTR-CDs (10, 30 and 50 mg/L) on growth of FG with respect to various plant growth parameters.

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Thin films of p-terphenyl luminophors doped by varying amounts of anthracene were prepared by using spin coating technique. The morphological, structural, and photophysical investigation of thin films of p-terphenyl as a function of anthracene concentration is studied by using scanning electron microscopy (SEM), X-ray diffraction (XRD), fluorescence spectroscopy and fluorescence microscopy. The results of XRD and SEM studies indicated that the doped p-terphenyl thin film is homogeneous as compared with a bare p-terphenyl thin film.

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The data article (vegetative plant propagation) culture techniques are sustainable alternatives to the large-scale production of economically important plant species. is an essential species that is mainly considered to be economically important due to their potential use as silk production, medicine and food. In this work, we evaluated the data of effects of different concentration of Waste Tea Residue Carbon Dots (WTR-CDs) on the ex vitro growth of morus.

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