Bismuth-based metal-organic framework (Bi-MOF) materials have shown potential for treating organic pollutants. In this work, multifunctional textiles were produced by synthesis of CAU-17 on carboxymethylated cotton fabrics by solvothermal and ultrasonic strategies and employed as recyclable photocatalysts. The compositional and structural features of the dense MOF crystal coatings on cotton fibers were confirmed by scanning electron microscopy, X-ray diffraction, and other characterization approaches.
View Article and Find Full Text PDFPolyolefins are a widely accepted commodity polymer made from olefinic monomer consisting of carbon and hydrogen. This thermoplastic polymeric material is formed through reactive double bonds of olefins by the addition polymerization technique and it possesses a diverse range of unique features for a large variety of applications. Among the various types, polyethylene and polypropylene are the prominent classes of polyolefins that can be crafted and manipulated into diversified products for numerous applications.
View Article and Find Full Text PDFWe investigated the additive ionic liquid (IL) type dependence on the crystal structure of poly(vinylidene fluoride) (PVDF) nanofibers. As additive ILs, we used imidazolium based ILs with different cation and anion sizes. From differential scanning calorimetry (DSC) measurements, we found that there is a proper amount for the additive IL to promote PVDF crystallization, and the proper amount is influenced by the cation size, not by the anion size.
View Article and Find Full Text PDFPolyvinyl alcohol/beryllium sulfate/polyethyleneimine (PVA/BeSO/PEI) precursor nanofibers (NFs) was first fabricated to obtain PVA/BeSO/PEI electrospun NFs by electrospinning technology, finally manufactured beryllium oxide (BeO) NFs followed by various heat treatment methods. The minimum calcination temperature for pure BeO NFs was 1000 °C, and the minimum specific surface area (5.1 m g) and pore volumes (0.
View Article and Find Full Text PDFThis study reports on the efficient methylene blue (MB) dye removal properties of a polyvinyl butyral (PVB)-amorphous titania (amTiO) hybrid fiber (PVB-amTiOF) made by air-gap spinning in acetone solvent. The successful fabrication of PVB-amTiOF was confirmed by employing Fourier transform infrared, scanning electron microscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and energy dispersive X-ray measurement. Batch experiments were used to examine the cationic MB dye adsorption performance in the dark.
View Article and Find Full Text PDFWe prepared low-density polyethylene (LDPE) nanofiber, a few hundred nanometers in diameter, using polyvinyl butyral (PVB) and a laser melt-electrospinning (M-ESP) device. We blended PVB with LDPE via an internal melt mixer, removed the PVB after M-ESP by ethanol treatment, and studied the influence of PVB on fiber diameter. A substantial diameter reduction with improved crystallinity of LDPE fiber was observed with increased PVB content in the blend.
View Article and Find Full Text PDFIn this work, a simple binary oxygen-deficient BiO oxide was prepared, and its crystal structure, optical property, band structure and electronic structure were systematically investigated. Plane-wave-based density functional theory (DFT) calculations were also carried out to determine that BiO is a typical indirect-gap semiconductor with the bandgap of 1.1 eV.
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