Lipid oxidation in emulsions is hypothesised to increase with decreasing droplet size, as this increases the specific oil-water interfacial area, where lipid oxidation is expected to be initiated. In literature, however, contradictory results have been reported, which can be caused by confounding factors such as the oil droplet polydispersity and the distribution of components between the available phases. In this work, monodisperse surfactant-stabilised emulsions with highly controlled droplet sizes of 4.
View Article and Find Full Text PDFHypothesis: The shelf life of multiphase systems, e.g. oil-in-water (O/W) emulsions, is severely limited by physical and/or chemical instabilities, which degrade their texture, macroscopic appearance, sensory and (for edible systems) nutritional quality.
View Article and Find Full Text PDFMicrofluidic emulsification has the potential to produce emulsions with very controlled droplet sizes in a subtle manner. To support in unleashing this potential, we provide guidelines regarding upscaling based on the performance of Upscale Partitioned EDGE (UPE) devices, using rapeseed oil as the to-be-dispersed phase and whey proteins as the emulsifier. The UPE device (11,000 droplet formation units (DFUs) of 5 × 1 µm) produced 3.
View Article and Find Full Text PDFLipid oxidation is a major factor limiting the shelf life of food and other emulsion products. In this work, we explore which lipid oxidation products may transfer between oil droplets in model food emulsions stabilized by excess amounts of surfactant, and whether this affects the overall reaction. No significant differences in concentrations of triglyceride-bound hydroperoxides were found before and after mixing 'clean' oil droplets with pre-oxidized ones.
View Article and Find Full Text PDFLipid oxidation is a well-recognized issue in dried food emulsions, such as infant milk formula. Antioxidants can be used to mitigate this issue; however, their efficiency in such complex systems is far from understood. In this study, antioxidant polarity is varied through the alkyl chain length of gallic acid esters (0-16 carbon atoms) incorporated to O/W emulsions that are subsequently spray-dried.
View Article and Find Full Text PDFThe partitioned EDGE droplet generation device is known for its' high monodisperse droplet formation frequencies in two distinct pressure ranges, and an interesting candidate for scale up of microfluidic emulsification devices. In the current study, we test various continuous and dispersed phase properties and device geometries to unravel how the device spontaneously forms small monodisperse droplets (6-18 μm) at low pressures, and larger monodisperse droplets (>28 μm) at elevated pressures. For the small droplets, we show that the continuous phase inflow in the droplet formation unit largely determines droplet formation behaviour and the resulting droplet size and blow-up pressure.
View Article and Find Full Text PDFBackground: Diagnosing IBD in horses is challenging and requires a multimodal approach, since no conclusive diagnostic test is available. The objectives of this study were to provide an overview of population characteristics, results of applied diagnostic tests, treatment modalities and outcome in a large group of horses thought to have IBD and that were presented to four large equine referral hospitals, and to provide an exploratory investigation of possible associations between results of applied diagnostic tests, applied treatment modalities and outcome. A retrospective case series was performed across four large equine referral hospitals.
View Article and Find Full Text PDFClogging is one of the main failure mechanisms encountered in industrial processes such as membrane filtration. Our understanding of the factors that govern the build-up of fouling layers and the emergence of clogs is largely incomplete, so that prevention of clogging remains an immense and costly challenge. In this paper we use a microfluidic model combined with quantitative real-time imaging to explore the influence of pore geometry and particle interactions on suspension clogging in constrictions, two crucial factors which remain relatively unexplored.
View Article and Find Full Text PDFCarbon Balance Manag
November 2013
Background: Trends in Alaska ecosystem carbon fluxes were predicted from inputs of monthly MODerate resolution Imaging Spectroradiometer (MODIS) vegetation index time-series combined with the NASA-CASA (Carnegie Ames Stanford Approach) carbon cycle simulation model over the past decade. CASA simulates monthly net ecosystem production (NEP) as the difference in carbon fluxes between net primary production (NPP) and soil microbial respiration (Rh).
Results: Model results showed that NEP on a unit area basis was estimated to be highest (> +10 g C m-2 yr-1) on average over the period 2000 to 2010 within the Major Land Resource Areas (MRLAs) of the Interior Brooks Range Mountains, the Arctic Foothills, and the Western Brooks Range Mountains.
Carbon Balance Manag
September 2013
Background: The objective of this study was to demonstrate a new, cost-effective method to define the sustainable amounts of harvested wood products in Southeast Asian countries case studies, while avoiding degradation (net loss) of total wood carbon stocks. Satellite remote sensing from the MODIS sensor was used in the CASA (Carnegie Ames Stanford Approach) carbon cycle model to map forest production for the Southeast Asia region from 2000 to 2010. These CASA model results have been designed to be spatially detailed enough to support carbon cycle assessments in different wooded land cover classes, e.
View Article and Find Full Text PDFBackground: A simulation model based on remote sensing data for spatial vegetation properties has been used to estimate ecosystem carbon fluxes across Yellowstone National Park (YNP). The CASA (Carnegie Ames Stanford Approach) model was applied at a regional scale to estimate seasonal and annual carbon fluxes as net primary production (NPP) and soil respiration components. Predicted net ecosystem production (NEP) flux of CO2 is estimated from the model for carbon sinks and sources over multi-year periods that varied in climate and (wildfire) disturbance histories.
View Article and Find Full Text PDFMany eukaryotic transcription factors induce DNA bending on binding to their recognition sequences. DNA bending could play a structural role by altering contacts between the protein and DNA. Alternatively, DNA bending could play a more direct role in transcription activation.
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