ZnCr₂O₄ Inclusions in ZnO Matrix Investigated by Probe-Corrected STEM-EELS.

The ZnCr₂O₄/ZnO materials system has a wide range of potential applications, for example, as a photocatalytic material for waste-water treatment and gas sensing. In this study, probe-corrected high-resolution scanning transmission electron microscopy and geometric phase analysis were utilized to study the dislocation structure and strain distribution at the interface between zinc oxide (ZnO) and embedded zinc chromium oxide (ZnCr₂O₄) particles. Ball-milled and dry-pressed ZnO and chromium oxide (α-Cr₂O₃) powder formed ZnCr₂O₄ inclusions in ZnO with size ~400 nm, where the interface properties depended on the interface orientation.