Cross-Linking of Polypropylene with Thiophene and Imidazole.

In this work, two novel routes to synthesis cross-linked polypropylene (PP) are introduced by using two different precursors (2-thiophenemethyl amine (TMA) and 1-(3 aminopropyl) imidazole (API)), both cross-linked with 1,1'-(methylenedi-4,1-phenylene) bismaleimide (BM) at two different annealing temperature values ( = 50 °C and = 150 °C). Both Diels-Alder (DA) and Michael addition reactions were successfully performed with TMA and API, respectively, albeit with different reactivity. Imidazole clearly shows a higher reactivity compared to thiophene.

Cross-Linking of Polypropylene via the Diels-Alder Reaction.

In this work, the possibility of preparing cross-linked polypropylene (PP) via Diels−Alder (DA) chemistry is explored. The overall strategy involves reaction of maleated polypropylene (the starting material), furfuryl amine (FFA), and bismaleimide (BM) as the cross-linking agent. The occurrence of reversible cross-linking was studied by checking the presence of relevant peaks in FTIR spectra, i.

A Morphology-Based Model to Describe the Low-Temperature Impact Behaviour of Rubber-Toughened Polypropylene.

The roles of the rubber particle size, the rubber particle size distribution and the constitutive behaviour of the isotactic polypropylene matrix have been studied by combining the Lazerri-Bucknall energy criterion for cavitation with the Van der Sanden-Meier-Tervoort ligament model adapted for impact conditions. It is concluded that an optimised morphology offers great potential to achieve enhanced mechanical properties with far less rubber and hence achieve a superior stiffness/toughness/processing balance.