The application of manganese complexes of ligands derived from 1,4,7-triazacyclononane in oxidative catalysis.

Since the disclosure that manganese complexes of certain azamacrocyclic ligands were potent low-temperature bleaching catalysts, considerable effort has focussed on their development towards the efficient catalytic oxidation of other substrates, principally with the environmentally benign oxidant H(2)O(2). These efforts have resulted in a broad substrate scope for the system, including alkenes (to give both epoxides and cis-diols as potential products), alcohols, sulfides and C-H oxidation. Additional developments include the heterogenisation of catalytic systems as well as the first generation of enantiomerically pure ligand systems for application in asymmetric epoxidation catalysis.