Introduction The evolution of computer-aided design/computer-aided manufacturing (CAD/CAM) systems has heightened the significance of digital models in dentistry, particularly for fabricating prostheses like inlays, crowns, and bridges. While digital dentistry offers enhanced speed and precision, the initial investment in intraoral scanners may pose a barrier for some clinicians. Extraoral or lab scanners, however, offer a viable alternative, reducing laboratory time and providing accurate prostheses fit, though challenges such as reflective surfaces and availability of scanning sprays persist, impacting scanning quality and operator technique.
View Article and Find Full Text PDFUnlabelled: The aim of this study is to evaluate how much the changes in the concrete mix design, which enable carbon footprint reduction, are impacting mechanical properties and predicted service life of concrete structure. The starting point of this study was concrete mix used in a recent reinforced concrete Pelješac Bridge in the Adriatic. In the first round of experiments the amount of cement in this initial mix was significantly lowered, without jeopardising workability of the mix.
View Article and Find Full Text PDFUsing the first-order perturbation theory and exciton-spin-orbit-photon-molecular-vibration-interaction (ESOPMVI) operator, the rates of reverse intersystem crossing (RISC) and thermally activated delayed fluorescence (TADF) are derived. It is shown that the pre-exponential factor of the rate of TADF is not an absolute constant as is commonly assumed. Instead, it depends on the square of the atomic number and the exchange energy, but it also depends on the triplet excitonic Bohr radius as , which enhances the rate of RISC by 4-6 orders of magnitude higher than the rate of the intersystem crossing, which undermines the dependence of the rate on the atomic number, and hence TADF can occur efficiently in metal-free organic solids.
View Article and Find Full Text PDFAim: To evaluate the effect of salivary contamination on the bond strength of one-bottle adhesive systems - (the V generation) at various stages during the bonding procedure and to investigate the effect of the contaminant removing treatments on the recovery of bond strengths.
Materials And Methods: In this study the V generation one-bottle system - (Adper Single Bond) was tested. Fifty caries-free human molars with flat dentin surfaces were randomly divided into five groups of ten teeth each: Group I had 15 second etching with 35% Ortho Phosphoric acid, 15 second rinse and blot dried (Uncontaminated); Group II contaminated and blot dried; Group III contaminated and completely dried; Group IV contaminated, washed, blot dried; Group V contaminated, retched washed, and blot dried.