Hybridisation of the cavity modes and the excitons to polariton states together with the coupling to the vibrational modes determine the linear optical properties of organic semiconductors in microcavities. In this article we compute the refractive index for such system using the Holstein-Tavis-Cummings model and determine then the linear optical properties using the transfer matrix method. We first extract the parameters for the exciton in our model from fitting to experimentally measured absorption of a 2,7-bis[9,9-di(4-methylphenyl)-fluoren-2-yl]-9,9-di(4-methylphenyl) fluorene (TDAF) molecular thin film.
View Article and Find Full Text PDFModifying the energy landscape of existing molecular emitters is an attractive challenge with favourable outcomes in chemistry and organic optoelectronic research. It has recently been explored through strong light-matter coupling studies where the organic emitters were placed in an optical cavity. Nonetheless, a debate revolves around whether the observed change in the material properties represents novel coupled system dynamics or the unmasking of pre-existing material properties induced by light-matter interactions.
View Article and Find Full Text PDFIn this Letter we investigate the concept of quantum work and its measurability from the viewpoint of quantum measurement theory. Very often, quantum work and fluctuation theorems are discussed in the framework of projective two-point measurement (TPM) schemes. According to a well-known no-go theorem, there is no work observable which satisfies both (i) an average work condition and (ii) the TPM statistics for diagonal input states.
View Article and Find Full Text PDFWe investigate a composite quantum collision model with measurements on the memory part, which effectively probe the system. The framework allows us to adjust the measurement strength, thereby tuning the dynamical map of the system. For a two-qubit setup with a symmetric and informationally complete measurement on the memory, we study the divisibility of the resulting dynamics in dependence of the measurement strength.
View Article and Find Full Text PDFWe study non-Markovian dynamics of an open quantum system system interacting with a nonstationary squeezed bosonic reservoir. We derive exact and approximate descriptions for the open system dynamics. Focusing on the spin boson model, we compare exact dynamics with Redfield theory and a quantum optical master equation for both short and long time dynamics and in non-Markovian and Markov regimes.
View Article and Find Full Text PDFThe coherence of an individual quantum state can be meaningfully discussed only when referring to a preferred basis. This arbitrariness can, however, be lifted when considering sets of quantum states. Here we introduce the concept of set coherence for characterizing the coherence of a set of quantum systems in a basis-independent way.
View Article and Find Full Text PDFWe solve two long-standing problems for stochastic descriptions of open quantum system dynamics. First, we find the classical stochastic processes corresponding to non-Markovian quantum state diffusion and non-Markovian quantum jumps in projective Hilbert space. Second, we show that the diffusive limit of non-Markovian quantum jumps can be taken on the projective Hilbert space in such a way that it coincides with non-Markovian quantum state diffusion.
View Article and Find Full Text PDFWe address the question of verifying the quantumness of thermal machines. A Szilárd engine is truly quantum if its work output cannot be described by a local hidden state model, i.e.
View Article and Find Full Text PDFWe derive a family of Gaussian non-Markovian stochastic Schrödinger equations for the dynamics of open quantum systems. The different unravelings correspond to different choices of squeezed coherent states, reflecting different measurement schemes on the environment. Consequently, we are able to give a single shot measurement interpretation for the stochastic states and microscopic expressions for the noise correlations of the Gaussian process.
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