The fate and toxicity of nanoplastics (NPs) in the environment is largely determined by their stability. We explored how water composition, nanoplastic size, and surface carboxyl group density influenced the aggregation of polystyrene (PS) NPs in fresh water. Unfunctionalized 200, 300, 500, and 1000 nm PS NPs and 310 nm carboxylated PS NPs with carboxyl group densities of 0.
View Article and Find Full Text PDFMicro- and nanoplastics (MNPs) are attracting increasing attention due to their persistence and potential ecological risks. This review critically summarizes the effects of photo-oxidation on the physical, chemical, and biological behaviors of MNPs in aquatic and terrestrial environments. The core of this paper explores how photo-oxidation-induced surface property changes in MNPs affect their adsorption toward contaminants, the stability and mobility of MNPs in water and porous media, as well as the transport of pollutants such as organic pollutants (OPs) and heavy metals (HMs).
View Article and Find Full Text PDFThe transport of viruses in groundwater is a complex process controlled by both hydrodynamic and reaction parameters. Characterizing the transport of viruses in groundwater is of crucial importance for investigating health risks associated with groundwater consumption from private individual or residential pumping wells. Setback distances between septic systems, which are the source of viruses, and pumping wells must be designed to offer sufficient groundwater travel times to allow the viral load to degrade sufficiently to be acceptable for community health needs.
View Article and Find Full Text PDFBiological ion exchange (BIEX) has proved to remove natural organic matter (NOM) better than biological activated carbon (BAC). This raises the question if BIEX can be integrated into a full-scale drinking water treatment plant to remove NOM and ammonia. In this study, a pilot plant consisting of one BIEX filter, three GAC filters and one BAC filter was set up as second-stage filtration at the Sainte-Rose drinking water treatment plant (Laval, Canada).
View Article and Find Full Text PDFCombining powdered activated carbon (PAC) with magnetic iron oxides has been proposed in the past to produce adsorbents for natural organic matter (NOM) removal that can be easily separated using a magnetic field. However, the trade-off between the iron oxides' benefits and the reduced carbon content, porosity, and surface area has not yet been investigated systematically. We produced 3 magnetic powdered activated carbons (MPAC) with mass fractions of 10%, 38% and 54% maghemite nanoparticles and compared them to bare PAC and pure nanoparticles with respect to NOM adsorption kinetics and isotherms.
View Article and Find Full Text PDFCombining the high adsorption capacity of powdered activated carbon (PAC) with magnetic properties of iron oxide nanoparticles (NPs) leads to a promising composite material, magnetic PAC or MPAC, which can be separated from water using magnetic separators. We propose MPAC as an alternative adsorbent in the biological hybrid membrane process and demonstrate that PAC covered with magnetic NPs is suitable as growth support for heterotrophic and nitrifying bacteria. MPAC with mass fractions of 0; 23; 38 and 54% maghemite was colonized in small bioreactors for over 90 days.
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