Publications by authors named "Ki-Sub Kim"

Background And Purpose: The effects of high-intensity interval training (HIIT) interventions on functional brain changes in older adults remain unclear. This preliminary study aimed to explore the effect of physical exercise intervention (PEI), including HIIT, on cognitive function, physical performance, and electroencephalogram patterns in Korean elderly people.

Methods: We enrolled six non-dementia participants aged >65 years from a community health center.

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Cadmium telluride (CdTe) nanoparticles (NPs) are known for their unique physical and chemical properties. NP synthesis via a size-controlled procedure has become an intriguing research topic because NPs exhibit novel optical and physical properties depending on their size. Their sizes and properties can vary depending on the types and concentrations of stabilizers, which are bound to the surface of the NPs and protect the NPs from aggregation.

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We present a design of a nanoscale inertial measurement unit or a data archive using a graphene-nanoflake (GNF) sandwiched between crossed graphene-nanoribbon (GNR) junctions. When an external force applied is below the retracting force, the inertial force exerted on the movable GNF can telescope it. Then, the self-restoring force increases as the attractive van der Waals force between the GNF and the GNRs, which enables the GNF to automatically and fully retract back into the sandwich position immediately after the externally applied force is released.

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There is a need for measures that can prevent the onset of dementia in the rapidly aging population. Reportedly, sustained physical exercise can prevent cognitive decline and disability. This study aimed to assess the feasibility of a 12-week physical exercise intervention (PEI) for delay of cognitive decline and disability in the at-risk elderly population in Korea.

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Superlubric motions of graphene nanoflakes (GNFs) on graphene have opened up more applications of graphene for micromachines and nanomachines. Here, we investigate the dynamic behavior of a GNF shuttle on a graphene nanoribbon (GNR) with carbon nanotube (CNT) blocks via molecular dynamics simulations. The GNF moves on a GNR superlubrically, and the CNTs as building blocks induce bistable potential wells so that the GNF is stabilized.

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Superlubricity in nanoscale graphene structures has been of interest for developing graphene-based nanoelectromechanical systems, as well as for the study of basic mechanical properties. Here, we investigated the translational and rotational motions of a square graphene nanoflake with retracting motions by performing classical molecular dynamics simulations. Our results show that the kinetic energy of the translational motion was exchanged into the kinetic energy of the rotational motion.

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Partially side-opened carbon nanopeapods show great potential for various applications. Here, we investigated the schematics and energetics of a nonvolatile nanomemory element, based on a C60 fullerene encapsulated in a partially opened carbon nanopeapod, using empirical interatomic interaction potential functions. Bistability of the van der Waals potential energy is achieved from the positional change of the encapsulated C60 fullerene, and the encapsulated C60 fullerene can shuttle between bistable positions, under alternatively applied force fields.

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Thiol-capped cadmium telluride (CdTe) nanoparticles (NPs) self-assembled into nanowires (NWs) under dark conditions, and the evolutionary process was investigated. Thiolglycolic acid (TGA) was selected as one of the stabilizers and a TGA-to-Cd ion ratio of 1.3 rather than the traditional 2.

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CdTe nanowires were synthesized from individual nanoparticles via self-assembly at a specific wavelength of light. The wavelength of 500 nm resulted in a self-assembly of nanoparticles into nanowires. Most of the produced nanowires were straight and long in shape and their length ranged from 300 nm to 20 µm.

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We have investigated the motion of a C60 molecule absorbed on sinusoidal graphene nanoflake (GNF) via molecular dynamics simulations. Since C60 deposited on sinusoidal GNF is favorable on energetic grounds, the C60 molecule moved toward one of the valleys of sinusoidal GNF without energy barrier. So no sooner the C60 molecule was deposited on the sinusoidal GNF, then the C60 molecule immediately began to move toward the valley of the sinusoidal GNF Since the position of the C60 molecule can be changed by externally applied force fields and has a binding energy of 0.

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Cadmium telluride (CdTe) nanowires were successfully synthesized from individual nanoparticles and the evolutionary process was investigated. Slow oxidation of Te(2-) in CdTe nanoparticles resulted in the generation of ribbons consisting of several layers of individual nanocrystals. The length of nanowires ranged from 1 to 8 μm.

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Cadmium telluride (CdTe) nanowires were successfully synthesized from individual nanoparticles via self-assembly, and the evolutionary process was investigated. The oxidation of tellurium ions in CdTe nanoparticles under dark conditions led to the assembly of straight nanowires made of several layers of individual nanoparticles. Transmission electron microscopy and scanning electron microscopy were performed to characterize the synthesized nanostructures.

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CdTe nanorribons were successfully synthesized from individual nanoparticle. Slow oxidation of Te(2-) in CdTe nanoparticles resulted in the assembly of ribbons consisting of several layers of individual nanocrystals. The light-controlled self-assembly of CdTe nanoparticles led to twisted ribbons with variable pitch.

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In this paper, we investigated the resonant frequencies of multi-walled carbon nanotube (MWCNT) resonators with short outertubes according to the classical molecular dynamics approach. The resonant frequencies of the MWCNT resonators with short outertubes were influenced in both the wall number and the length of the short outertubes. The resonance frequencies of MWCNTs with short outertubes could be modeled by Gaussian distribution functions.

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We have successfully synthesized ionic liquid (IL)-stabilized palladium (Pd) nanoparticles (NPs) by electrochemical reduction. The particle size was controlled by adjusting the current density. Transmission electron microscopic (TEM) images showed that the average diameters of the Pd NPs were 2.

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We conceptually investigated a carbon-nanotube-based tuner operated by the telescoping nanotube motion in a multi-walled carbon-nanotube induced by electromigration of an encapsulated nanoparticle. The telescoping lengths in the proposed carbon-nanotube-based tuner could be achieved from the electromigration phenomena of the nanoparticle embedded in the carbon nanotube. So the core part is the nanoparticle shuttle and a multi-walled carbon-nanotube with ultra-low interlayer friction.

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We investigate the nano mass transfer in an ultrahigh frequency carbon-nanotube-resonator encapsulating a nanocluster via classical molecular dynamics simulations. When the carbon-nanotube-resonator vibrated, the encapsulated copper nanocluster more rapidly approached the end of the cantilevered carbon-nanotube-resonator. Such phenomena were due to the migration of the encapsulated copper nanocluster due to the centrifugal force induced by the vibrating nanotube resonator.

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Pyrrolidinium cation-based ionic liquids were synthesized, and their inhibition effects on methane hydrate formation were investigated. It was found that the ionic liquids shifted the hydrate equilibrium line to a lower temperature at a specific pressure, while simultaneously delaying gas hydrate formation.

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We investigated a linear nanomotor based on the telescoping carbon nanotube motion induced by electromigration of an encapsulated nanoparticle. The nanoparticle motion induced by the electric current makes the inner nanotube linearly telescope or retreat. Theoretical results using a kinetic Monte Carlo method were in good agreement with previous experiments.

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Metal nanoparticles were successfully synthesized from the self-regulated reduction of hydroxylated ionic liquids in aqueous phase without additives. A new water-phase synthesis of gold and palladium nanoparticles using N-(2-hydroxyethyl)-N-methylmorpholinium tetrafluoroborate is described. Transmission electron microscopy was performed to characterize the metal nanoparticles.

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The collective properties of nanoparticles manifest in their ability to self-organize into complex microscale structures. Slow oxidation of tellurium ions in cadmium telluride (CdTe) nanoparticles results in the assembly of 1- to 4-micrometer-long flat ribbons made of several layers of individual cadmium sulfide (CdS)/CdTe nanocrystals. Twisting of the ribbons with an equal distribution of left and right helices was induced by illumination with visible light.

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Poly(vinylidenefluoride)-hexafluoropropylene (PVdF(HFP))-ionic liquid gel electrolytes were prepared using ionic liquids based on 1-(2-hydroxyethyl)-3-methyl imidazolium tetrafluoroborate and 1-(2-hydroxyethyl)-3-methyl imidazolium hexafluorophosphate. A conventional metathesis reaction was used to prepare these ionic liquids, which have high purity and exhibit a liquid state at room temperature. The prepared polymer-ionic liquid gel proved to be a free-standing and rubbery film in which the degree of transparency differed according to the ratio and type of ionic liquid used.

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One-phase synthesis of gold and platinum nanoparticles using new thiol-functionalized ionic liquids (TFILs) is described for the first time. TFILs as stabilizing agents for gold and platinum nanoparticles were designed to have thiol groups on either the cation or anion and symmetrical or unsymmetrical positions only in the cation. Transmission electron microscopy, electron diffraction, and NMR were used for the characterization of nanoparticles.

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Ionic liquids based on N-alkyl-N-methylmorpholinium salts have been synthesized and the physical and electrochemical characteristics of this family of ionic liquids have been investigated for use as electrolytes.

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For the purpose of developing new disinfectants and antiseptics, we searched for compounds having high bactericidal activity against gram-positive bacteria, gram-negative bacteria, and fungi. Three different series of quaternary imidazolium and pyrrolidinonium salts were synthesized: series A (1-alkyl-3-methylimidazolium chlorides and bromides); series B (1-alkyl-2-methyl-3-hydroxyethylimidazolium chlorides); and series C (N-alkyl-N-hydroxyethylpyrrolidinonium). Series B and C were newly designed.

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