Assessment of photo electro-Fenton and solar photo electro-Fenton processes for the efficient degradation of asulam herbicide.

The degradation of asulam herbicide by photo electro-Fenton (PEF) and solar photo electro-Fenton (SPEF) processes was studied using an undivided electrochemical BDD/carbon-felt cell to generate HO continuously. A central composite design combined with response surface methodology was applied to determine the optimal operating conditions of current intensity = 0.30 A, [Fe] = 0.

Ecological risk assessment associated with five endocrine-disrupting compounds in wastewater treatment plants of Northeast Mexico.

The ecological risk associated with five endocrine-disrupting compounds (EDCs) was studied in four wastewater treatment plants (WWTPs) in Monterrey, Mexico. The EDCs, 17β-estradiol (E2), 17α-ethinylestradiol (EE2), bisphenol A (BPA), 4-nonylphenol (4NP), and 4-tert-octylphenol (4TOP) were determined by SPE/GC-MS method, where EE2 and 4TOP were the most abundant in effluents at levels from 1.6 - 26.

Development of an HPLC-DAD method for the simultaneous analysis of four xenoestrogens in water and its application for monitoring photocatalytic degradation.

A high-performance liquid chromatography with diode array detector (HPLC-DAD) method was developed and validated for the simultaneous quantification of 4 xenoestrogens in water for monitoring their photocatalytic degradation in synthetic water. The analytical parameters evaluated were linearity, limits of detection, and quantification (LODs and LOQs), selectivity, and accuracy, according to the US Food and Drug Administration (FDA) and Eurachem guidelines. The developed method shows good linearity (R > 0.

Occurrence and seasonal distribution of five selected endocrine-disrupting compounds in wastewater treatment plants of the Metropolitan Area of Monterrey, Mexico: The role of water quality parameters.

Five endocrine-disrupting compounds (EDCs) were determined in four urban wastewater treatment plants (WWTPs) of the Metropolitan Area of Monterrey (MAM) in two seasonal periods (winter and summer). The MAM, one of the most urbanized areas in Mexico, is characterized by high industrial activity and population density, leading to extensive use of several EDCs. In the MAM, ∼90% of urban and industrial wastewater is treated in WWTPs, where EDCs can be partially eliminated.

Removal of 17α-ethinylestradiol and caffeine from wastewater by UASB-Fenton coupled system.

In aquatic systems, some substances considered as endocrine disruptors have been detected, which can be due to their incomplete elimination in wastewater treatment plants (WWTPs) and inadequate disposal of pharmaceuticals. Among these contaminants are 17α-ethinylestradiol (EE2) and caffeine (CAF). Moreover, it has been reported that this kind of contaminants may provoke different adverse effects in many aquatic organisms.