Synthesis and Characterization of New Mesoporous Polyurethane-Nitrogen Doped Carbon Dot Nanocomposites: Ultrafast, Highly Selective and Sensitive Turn-off Fluorescent Sensors for Fe Ions.

A new fluorescent mesoporous polyurethane (PU) (9) was synthesized by reaction between 2,2'-(methylenebis(4,1-phenylene))bis(5-isocyanatoisoindoline-1,3-dione) (Diisocyanate) (5) and 4,4',4″-((1,3,5-triazine-2,4,6-triyl)tris (azanediyl))triphenol (Triol, TO) (8) (molar ratio 3:2). PU was characterized by using FT-IR, H-NMR, XRD, UV-Vis, TGA, Nitrogen adsorption-desorption isotherm, BET, FE-SEM and Photoluminescence (PL) analyses. To the best of our knowledge, this is the first time that a fluorescent polyurethane has been made without the use of commercial fluorescent materials.

Designed biocompatible nano-inhibitor based on poly(β-cyclodextrin-ester) for reduction of the DEHP migration from plasticized PVC.

The easy migration of di(2-ethylhexyl) phthalate (DEHP) from the plasticized PVC (P-PVC) poses a serious threat to human health and the ecosystems. Thus, its control migration from the P-PVC products is very important. In this work, a poly(β-cyclodextrin-ester) network (β-CDP) was synthesized via reaction of β-cyclodextrin with 3,3',4,4'-benzophenone tetracarboxylic dianhydride.

Synthesis and characterization of fast-swelling porous superabsorbent hydrogel based on starch as a hemostatic agent.

The body can't control massive bleeding without treatment. Different hemostatic agents have been prepared recently, but most of them are ineffective in severe bleeding and expensive or cause safety concerns. In this study, in order to achieve fast control of bleeding, we synthesized and characterized fast-swelling porous superabsorbent hydrogel (FSPSH) and investigated its use as a hemostatic agent.

Pseudo five-component synthesis of bis-alpha-acyloxy-beta-diketo amides from diimide-dicarboxylic acids.

Diimide-dicaboxylic acids derived from condensation of alpha-amino acids with the 2,3,5,6-bicyclo[2.2.2] oct-2-enetetracarboxylic-2,3:5,6-dianhydride or 1,2,4,5- bezenetetracarboxylic-1,2:4,5-dianhydride react with ninhydrin and isocyanides to produce some novel interesting bis-alpha-acyloxy-beta-diketo amides.

Synthesis of some new 2,5-disubstituted 1,3,4-thiadiazoles containing isomeric pyridyl as potent antimicrobial agents.

Several new 2,5-disubstituted derivatives of 1,3,4-thiadiazoles containing isomeric pyridyl were obtained from cyclization of corresponding thiosemicarbazides under acidic conditions. The newly synthesized compounds were characterized using different methods of spectroscopy such as IR, 1H-NMR, 13C-NMR, MS and elemental analysis. The minimal inhibitory concentration (MIC) results of screening of some of the synthesized compounds were also reported.