Unifying the temperature dependent dynamics of glass formers.

Strong changes in bulk properties, such as modulus and viscosity, are observed near the glass transition temperature, Tg, of amorphous materials. For more than a century, intense efforts have been made to define a microscopic origin for these macroscopic changes in properties. Using transition state theory (TST), we delve into the atomic/molecular level picture of how microscopic localized unit relaxations, or "cage rattles," evolve to macroscopic structural relaxations above Tg.

Bulk Biopolyelectrolyte Complexes from Homopolypeptides: Solid "Salt Bridges".

Salt bridges, pairings between oppositely charged amino acids, are dispersed throughout proteins to assist folding and interactions. Biopolyelectrolyte complexes (BioPECs) were made between the homopolypeptides poly-l-arginine (PLR) and poly-l-lysine (PLK) with sodium triphosphate (STPP), as well as from polypeptide-only combinations. Viscoelastic measurements on these high salt bridge density materials showed many were solid, even glassy, in nature.

Gummy Nanoparticles with Glassy Shells in Electrostatic Nanocomposites.

Nanocomposites with unusual and superior properties often contain well-dispersed nanoparticles. Polydimethylsiloxane, PDMS, offers a fluidlike or rubbery (when cross-linked) response, which complements the high-modulus nature of inorganic nanofillers. Systems using PDMS as the nanoparticulate, rather than the continuous, phase are rare because it is difficult to make PDMS nanoparticles.