The mechanisms linking perceived stress to pilots' safety attitudes: a chain mediation effect of job burnout and cognitive flexibility.

Introduction: Pilots' safety attitude is crucial for aviation safety. Current research shows a correlation between perceived stress and safety attitude, yet the mechanism underlying this association remains unclear. Against the backdrop of heightened attention to pilots' stress, this study aims to thoroughly explore the inherent connection between pilot safety attitudes and their perceived stress, offering targeted insights into preventing and addressing safety attitude issues arising from pilot stress.

Dioxane promoted photochemical -alkylation of 1,3-dicarbonyl compounds beyond carbene insertion into C-H and C-C bonds.

A photochemical synthesis of enol ethers and furan-3(2)-ones from 1,3-dicarbonyl compounds and aryl diazoacetates has been developed. Significantly, 1,4-dioxane promoted -alkylation of various 1,3-dicarbonyl compounds beyond previous carbene insertion into C-H and C-C bonds has been disclosed.

Exploring the measurement of psychological resilience in Chinese civil aviation pilots based on generalizability theory and item response theory.

Understanding and accurately measuring resilience among Chinese civil aviation pilots is imperative, especially concerning the psychological impact of distressing events on their well-being and aviation safety. Despite the necessity, a validated and tailored measurement tool specific to this demographic is absent. Addressing this gap, this study built on the widely used CD-RISC-25 to analyze and modify its applicability to Chinese civil aviation pilots.

Base-free regio- and stereoselective photochemical synthesis of enol ethers from 1,3-dicarbonyl compounds.

A visible light-induced kinetic controlled regioselective -alkylation of various 1,3-dicarbonyl compounds with diazoacetates and cyclic ethers has been developed. The protocol provides a green and practical approach to highly stereoselective enol ethers under mild and base-free conditions in good to excellent yields.

Fano Resonance in Near-Field Thermal Radiation of Two-Dimensional Van der Waals Heterostructures.

Two-dimensional (2D) materials and their vertically stacked heterostructures have attracted much attention due to their novel optical properties and strong light-matter interactions in the infrared. Here, we present a theoretical study of the near-field thermal radiation of 2D vdW heterostructures vertically stacked of graphene and monolayer polar material (2D hBN as an example). An asymmetric Fano line shape is observed in its near-field thermal radiation spectrum, which is attributed to the interference between the narrowband discrete state (the phonon polaritons in 2D hBN) and a broadband continuum state (the plasmons in graphene), as verified by the coupled oscillator model.

Thermal Insulation Performance of Aerogel Nano-Porous Materials: Characterization and Test Methods.

Due to the extremely high porosity and extremely low density of nano-porous thermal insulation materials, the characteristic size of the pores inside the materials and the characteristic size of the solid skeleton structure are on the nanometer scale, which leads to the obvious nanoscale effect of the heat transfer law inside the aerogel materials. Therefore, the nanoscale heat transfer characteristics inside the aerogel materials and the existing mathematical models for calculating the thermal conductivity of various heat transfer modes at the nanoscale need to be summarized in detail. Moreover, in order to verify the accuracy of the thermal conductivity calculation model of aerogel nano-porous materials, correct experimental data are required to modify the model.

Influencing factors of novice pilot SA based on DEMATEL-AISM method: From pilots' view.

Pilot situation awareness (SA) regulates flight safety, and inexperience may impair novice pilot reliability in SA. This study aims to determine the key influencing factors of novice pilot SA and to analyze the interrelationship and interaction mechanism of the factors. We investigated 55 novice pilots trained at aviation schools and identified the influencing factor index system by the Delphi survey.

Visible light-induced carbene reactivity of acceptor diazoalkanes: deconstructive difunctionalizations of cyclic ethers with nucleophiles.

A visible light-induced carbene reactivity of acceptor diazoalkanes has been developed for the synthesis of difunctionalized ethers from cyclic ethers and various N/O/S nucleophiles.

Photocatalytic Regioselective Difunctionalization of Alkenes with Diazo Compounds and -Butyl Nitrite: Access to γ-Oximino Esters.

A visible-light photocatalytic regioselective difunctionalization of alkenes with diazo compounds and -butyl nitrite has been developed. The protocol provides an efficient approach to γ-oximino esters under mild conditions. Significantly, this transformation not only shows the good compatibility of nucleophilic diazo compounds and electrophilic -butyl nitrite but also displays diazo compounds generating alkyl radicals that preferred addition to alkenes over nitroso radicals.

Visible Light-Promoted Diazoacetates and Nitriles Generating Nitrilium Ions Trapped by Benzotriazoles and Carboxylic Acids.

A visible light-promoted generation of nitrilium ions from diazoacetates and nitriles has been developed. The reaction utilized visible light transformation of diazoacetates to the free carbene that could be trapped by nitriles to generate nitrilium ions, followed by nucleophilic attack on the benzotriazoles and carboxylic acids. This protocol provides an efficient and practical approach to -imidoylbenzotriazoles and diacylglycine esters in good to excellent yields.

Numerical Study of the Influence of Coupling Interface Emissivity on Aerogel Metal Thermal Protection Performance.

For aerogels in metal thermal protection system (MTPS), radiative heat transfer will participate in the thermal transport process. Therefore, the influence of the emissivity of the coupling interface between metal and aerogels on thermal insulation performance is considered an important research focus. In this paper, CFD numerical simulation is performed to study the influence of emissivity on the performance with different extinction coefficients at different boundary temperatures.

Merging Gold/Copper Catalysis and Copper/Photoredox Catalysis: An Approach to Alkyl Oxazoles from -Propargylamides.

Here, we report a mild and highly efficient approach to alkyl oxazoles through merging gold/copper catalysis and copper/photoredox catalysis. Various alkyl oxazoles are synthesized from -propargylamides with alkyl halides in good to excellent yields with wide functional-group compatibility under blue-light irradiation. Significantly, a copper catalyst plays a dual role in this transformation: as a powerful cocatalyst to accelerate protodeauration of vinyl gold intermediates and improve photoredox catalysis.

Symmetric metasurface with dual band polarization-independent high-Q resonances governed by symmetry-protected BIC.

In this Letter, we propose a symmetric metasurface composed of single-sized amorphous-silicon (a-Si) cuboids tetramer clusters that support two resonances with opposite symmetry, i.e., in-plane magnetic dipole (MD) resonance and in-plane toroidal dipole (TD) resonance governed by symmetry-protected bound states in the continuum (SP-BIC) in the near-infrared region.

Geometrical effect of graded index on the transport of polarized lights.

We investigate the geometrical effect of graded index on the transport of polarized lights in the scope of geometrical optics, and present three effective methods based on the Runge-Kutta ray tracing technique in the Frenet-Serret frame and a fixed global Cartesian frame, respectively, for obtaining the polarization state of a polarized light that propagates in graded-index media. The three methods have their own advantages in accuracy, computational efficiency, and difficulty of implementation, respectively. Simulations on a three-dimensional graded-index model show that the results obtained by the three methods are in perfect agreement with each other.

Direction-independent dual-band perfect absorption induced by fundamental magnetic polaritons.

In this paper, we designed a single sized Metal-Insulator Pair-Metal hybrid grating for dual-band perfect absorption from 8 μm to 14 μm utilizing both nondispersive insulators and dispersive phonic insulators. The hybrid grating was composed of Al/ZnTe-SiC pair/Al, which incorporated an ultrathin phononic SiC layer between the nondispersive ZnTe dielectric spacer and Al substrate. The physical mechanisms responsible for the dual-band perfect absorption were elucidated by the resonance of fundamental magnetic polaritons (MPs).

Near-field radiative transfer between magneto-dielectric uniaxial anisotropic media.

We investigate the near-field radiative heat transfer between two semi-infinite magneto-dielectric uniaxial anisotropic media (MDUAM). SiC nanowires embedded in metamaterials are used to implement electric and magnetic anisotropy, which leads to the hyperbolic dispersion relation for both TE and TM waves. The results show that the TM and TE waves can support both hyperbolic modes and surface modes and that there exist additional modes contributing to the heat transfer for TE waves.