Thermal and Mechanical Mechanisms of Polymer Wear at the Nanoscale.

Wear is a ubiquitous phenomenon that limits the life of many engineered components with sliding interfaces through the gradual removal of material. The wear of polymers is crucial in many applications, ranging from bearings to orthopedic implants to nanolithography processes. The wear rate of polymers is strongly affected by the stress and temperature at the interface.

Identifying Heterogeneous Micromechanical Properties of Biological Tissues via Physics-Informed Neural Networks.

The heterogeneous micromechanical properties of biological tissues have profound implications across diverse medical and engineering domains. However, identifying full-field heterogeneous elastic properties of soft materials using traditional engineering approaches is fundamentally challenging due to difficulties in estimating local stress fields. Recently, there has been a growing interest in data-driven models for learning full-field mechanical responses, such as displacement and strain, from experimental or synthetic data.

Bellybutton: accessible and customizable deep-learning image segmentation.

The conversion of raw images into quantifiable data can be a major hurdle and time-sink in experimental research, and typically involves identifying region(s) of interest, a process known as segmentation. Machine learning tools for image segmentation are often specific to a set of tasks, such as tracking cells, or require substantial compute or coding knowledge to train and use. Here we introduce an easy-to-use (no coding required), image segmentation method, using a 15-layer convolutional neural network that can be trained on a laptop: Bellybutton.

Identifying heterogeneous micromechanical properties of biological tissues via physics-informed neural networks.

The heterogeneous micromechanical properties of biological tissues have profound implications across diverse medical and engineering domains. However, identifying full-field heterogeneous elastic properties of soft materials using traditional engineering approaches is fundamentally challenging due to difficulties in estimating local stress fields. Recently, there has been a growing interest in using data-driven models to learn full-field mechanical responses such as displacement and strain from experimental or synthetic data.

Biomechanical Impact of Pathogenic MYBPC3 Truncation Variant Revealed by Dynamically Tuning In Vitro Afterload.

Engineered cardiac microtissues were fabricated using pluripotent stem cells with a hypertrophic cardiomyopathy associated c. 2827 C>T; p.R943x truncation variant in myosin binding protein C (MYBPC3).

A mechanics-based approach to realize high-force capacity electroadhesives for robots.

Materials with electroprogrammable stiffness and adhesion can enhance the performance of robotic systems, but achieving large changes in stiffness and adhesive forces in real time is an ongoing challenge. Electroadhesive clutches can rapidly adhere high stiffness elements, although their low force capacities and high activation voltages have limited their applications. A major challenge in realizing stronger electroadhesive clutches is that current parallel plate models poorly predict clutch force capacity and cannot be used to design better devices.

Versatile Adhesion-Based Gripping via an Unstructured Variable Stiffness Membrane.

Reversible and variable dry adhesion is a promising approach for versatile robotic grasping. Variable stiffness materials with a modulus that can be tuned using an external stimulus offer a unique approach to realize dynamic control of adhesion. In this study, an unstructured shape memory polymer (SMP) membrane with variable stiffness is used to pick-and-place three-dimensional objects.

Role of Molecular Layering in the Enhanced Mechanical Properties of Stable Glasses.

The density, degree of molecular orientation, and molecular layering of vapor-deposited stable glasses (SGs) vary with substrate temperature () below the glass-transition temperature (). Density and orientation have been suggested to be factors influencing the mechanical properties of SGs. We perform nanoindentation on two molecules which differ by only a single substituent, allowing one molecule to adopt an in-plane orientation at low .

The Interplay of Polymer Bridging and Entanglement in Toughening Polymer-Infiltrated Nanoparticle Films.

Polymer-nanoparticle composite films (PNCFs) with high loadings of nanoparticles (NPs) (>50 vol %) have applications in multiple areas, and an understanding of their mechanical properties is essential for their broader use. The high-volume fraction and small size of the NPs lead to physical confinement of the polymers that can drastically change the properties of polymers relative to the bulk. We investigate the fracture behavior of a class of highly loaded PNCFs prepared by polymer infiltration into NP packings.

Humidity dependence of fracture toughness of cellulose fibrous networks.

Cellulose-based materials are increasingly finding applications in technology due to their sustainability and biodegradability. The sensitivity of cellulose fiber networks to environmental conditions such as temperature and humidity is well known. Yet, there is an incomplete understanding of the dependence of the fracture toughness of cellulose networks on environmental conditions.

Magnetic field tuning of mechanical properties of ultrasoft PDMS-based magnetorheological elastomers for biological applications.

We report tuning of the moduli and surface roughness of magnetorheological elastomers (MREs) by varying applied magnetic field. Ultrasoft MREs are fabricated using a physiologically relevant commercial polymer, Sylgard 527, and carbonyl iron powder (CIP). We found that the shear storage modulus, Young's modulus, and root-mean-square surface roughness are increased by ~41×, ~11×, and ~11×, respectively, when subjected to a magnetic field strength of 95.

Materials with Electroprogrammable Stiffness.

Stiffness is a mechanical property of vital importance to any material system and is typically considered a static quantity. Recent work, however, has shown that novel materials with programmable stiffness can enhance the performance and simplify the design of engineered systems, such as morphing wings, robotic grippers, and wearable exoskeletons. For many of these applications, the ability to program stiffness with electrical activation is advantageous because of the natural compatibility with electrical sensing, control, and power networks ubiquitous in autonomous machines and robots.

Polymer-infiltrated nanoplatelet films with nacre-like structure flow coating and capillary rise infiltration (CaRI).

Alignment of highly anisotropic nanomaterials in a polymer matrix can yield nanocomposites with unique mechanical and transport properties. Conventional methods of nanocomposite film fabrication are not well-suited for manufacturing composites with very high concentrations of anisotropic nanomaterials, potentially limiting the widespread implementation of these useful structures. In this work, we present a scalable approach to fabricate polymer-infiltrated nanoplatelet films (PINFs) based on flow coating and capillary rise infiltration (CaRI) and study the processing-structure-property relationship of these PINFs.

Versatile Soft Robot Gripper Enabled by Stiffness and Adhesion Tuning via Thermoplastic Composite.

Within the field of robotics, stiffness tuning technologies have potential for a variety of applications-perhaps most notably for robotic grasping. Many stiffness tuning grippers have been developed that can grasp fragile or irregularly shaped objects without causing damage and while still accommodating large loads. In addition to limiting gripper deformation when lifting an object, increasing gripper stiffness after contact formation improves load sharing at the interface and enhances adhesion.

Adhesion of flat-ended pillars with non-circular contacts.

Fibrillar adhesives composed of fibers with non-circular cross-sections and contacts, including squares and rectangles, offer advantages that include a larger real contact area when arranged in arrays and simplicity in fabrication. However, they typically have a lower adhesion strength compared to circular pillars due to a stress concentration at the corner of the non-circular contact. We investigate the adhesion of composite pillars with circular, square and rectangular cross-sections each consisting of a stiff pillar terminated by a thin compliant layer at the tip.

Switchable Adhesion via Subsurface Pressure Modulation.

Materials and devices with tunable dry adhesion have many applications, including transfer printing, climbing robots, and gripping in pick-and-place processes. In this paper, a novel soft device to achieve dynamically tunable dry adhesion via modulation of subsurface pneumatic pressure is introduced. Specifically, a cylindrical elastomer pillar with a mushroom-shaped cap and annular chamber that can be pressurized to tune the adhesion is investigated.

Strong, Ultralight Nanofoams with Extreme Recovery and Dissipation by Manipulation of Internal Adhesive Contacts.

Advances in three-dimensional nanofabrication techniques have enabled the development of lightweight solids, such as hollow nanolattices, having record values of specific stiffness and strength, albeit at low production throughput. At the length scales of the structural elements of these solids-which are often tens of nanometers or smaller-forces required for elastic deformation can be comparable to adhesive forces, rendering the possibility to tailor bulk mechanical properties based on the relative balance of these forces. Herein, we study this interplay via the mechanics of ultralight ceramic-coated carbon nanotube (CNT) structures.

Thermal Degradation of Polystyrene under Extreme Nanoconfinement.

Extreme nanoconfinement has been shown to significantly affect the properties of materials. Here we demonstrate that extreme nanoconfinement can significantly improve the thermal stability of polystyrene (PS) and reduce its flammability. Capillary rise infiltration (CaRI) is used to infiltrate PS into films of randomly packed silica nanoparticles (NPs) to produce highly confined states.

Soft nanocomposite electroadhesives for digital micro- and nanotransfer printing.

Automated handling of microscale objects is essential for manufacturing of next-generation electronic systems. Yet, mechanical pick-and-place technologies cannot manipulate smaller objects whose surface forces dominate over gravity, and emerging microtransfer printing methods require multidirectional motion, heating, and/or chemical bonding to switch adhesion. We introduce soft nanocomposite electroadhesives (SNEs), comprising sparse forests of dielectric-coated carbon nanotubes (CNTs), which have electrostatically switchable dry adhesion.

Tunable and Reversible Substrate Stiffness Reveals a Dynamic Mechanosensitivity of Cardiomyocytes.

New directions in material applications have allowed for the fresh insight into the coordination of biophysical cues and regulators. Although the role of the mechanical microenvironment on cell responses and mechanics is often studied, most analyses only consider static environments and behavior, however, cells and tissues are themselves dynamic materials that adapt in myriad ways to alterations in their environment. Here, we introduce an approach, through the addition of magnetic inclusions into a soft poly(dimethylsiloxane) elastomer, to fabricate a substrate that can be stiffened nearly instantaneously in the presence of cells through the use of a magnetic gradient to investigate short-term cellular responses to dynamic stiffening or softening.

Toughening Nanoparticle Films via Polymer Infiltration and Confinement.

Disordered nanoparticle films have significant technological applications as coatings and membranes. Unfortunately, their use to date has been limited by poor mechanical properties, notably low fracture toughness, which often results in brittle failure and cracking. We demonstrate that the fracture toughness of TiO nanoparticle films can be increased by nearly an order of magnitude through infiltration of polystyrene into the film.

Ultrasensitive, Mechanically Responsive Optical Metasurfaces via Strain Amplification.

Optical metasurfaces promise ultrathin, lightweight, miniaturized optical components with outstanding capabilities to manipulate the amplitude, phase, and polarization of light compared to conventional, bulk optics. The emergence of reconfigurable metasurfaces further integrates dynamic tunability with optical functionalities. Here, we report a structurally reconfigurable, optical metasurface constructed by integrating a plasmonic lattice array in the gap between a pair of symmetric microrods that serve to locally amplify the strain created on an elastomeric substrate by an external mechanical stimulus.

Shear Adhesion of Tapered Nanopillar Arrays.

Tapered nanopillars with various cross sections, including cone-shaped, stepwise, and pencil-like structures (300 nm in diameter at the base of the pillars and 1.1 μm in height), are prepared from epoxy resin templated by nanoporous anodic aluminum oxide (AAO) membranes. The effect of pillar geometry on the shear adhesion behavior of these nanopillar arrays is investigated via sliding experiments in a nanoindentation system.

Spontaneous Periodic Delamination of Thin Films To Form Crack-Free Metal and Silicon Ribbons with High Stretchability.

Design of electronic materials with high stretchability is of great importance for realizing soft and conformal electronics. One strategy of realizing stretchable metals and semiconductors is to exploit the buckling of materials bonded to elastomers. However, the level of stretchability is often limited by the cracking and fragmentation of the materials that occurs when constrained buckling occurs while bonded to the substrate.