The effect of thermal annealing on low-temperature excess heat capacity was investigated in fresnoite (Ba2TiSi2O8) glass. The amplitudes of the excess heat capacity decreased, and their positions shifted to a higher temperature by relaxation or crystallization. In particular, we revealed that the change in the excess heat capacity during transition from the glassy state to the crystalline state is relatively small compared with that of other oxides.
View Article and Find Full Text PDFInelastic light scattering has been utilized for examining the structure of glass and its relaxation. However, the quasi-elastic-light-scattering (QLS) phenomenon has not been addressed in much detail. In this study, we observed pronounced QLS-intensity variations in two temperature domains-supercooled liquid (SCL) state (α-relaxation regime) and below the glass-transition temperature (β-relaxation regime)-in niobium-oxide (Nb(2)O(5))-rich glass.
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