In situ investigation of Pt(100--x)Au(x) and Pt(100--y)Sn(y) nanoalloys.

Dispersed sols of 1-10 nm sized Pt(100--x)Au(x) and Pt(100--y)Sn(y) nanoalloys have been prepared separately at various x and y above and below the miscibility limit in the bulk metals. Pt(100--x)Au(x) was derived from trisodium citrate reduction of aqueous solutions of H2PtCl6 and HAuCl4. Pt(100--y)-Sn(y) was produced by (i) complexing Sn2+ with glucose at 323 K at pH > 7, (ii) neutralising this with H2PtC16 addition and (iii) reducing the bimetallic precursor with glucose on raising the temperature to 373 K.