The functional layered organosilica materials prepared with anion surfactant templates.

A novel strategy for the synthesis of layered organosilica is demonstrated. The ionic interaction between the anionic group of a surfactant (sodium dodecyl sulfate) and the cationic organic group of an organosilane (3-aminopropyltrimethoxysilane, ATMS) under acidic conditions was utilized to create a layered organosilica at room temperature. The inorganic part of the organosilica layer was an Si-O hexagonal sheet, and organofunctional groups were alternately arranged on both sides of the sheet.

Dissolution-aggregation behavior of water-soluble nanographites and their adsorptive characteristics for 2-naphthol in aqueous solutions.

Carbon black was severely oxidized by concentrated nitric acid at 373 K, and the oxidation product was fractionated by ultrafiltration into five groups of a few nanometer-sized water-soluble aromatic compounds, which we called water-soluble nanographites (WSNG1-5). Most WSNGs dissolve in neutral and alkaline 0.1 moldm(-3) NaCl solutions, but precipitate in acidic solutions.