Modelling anaerobic sulfide removal by sulfide shuttling bacteria.

Sulfide oxidizing bacteria are used in industrial biodesulfurization processes to convert sulfide to sulfur. These bacteria can spatially separate sulfide removal from terminal electron transfer, thereby acting as sulfide shuttles. The mechanisms underlying sulfide shuttling are not yet clear.

Influence of oxidation-reduction potential and pH on polysulfide concentrations and chain lengths in the biological desulfurization process under haloalkaline conditions.

Biological desulfurization under haloalkaline conditions has been applied worldwide to remove hydrogen sulfide (HS) from sour gas steams. The process relies on sulfide-oxidizing bacteria (SOB) to oxidize HS to elemental sulfur (S), which can then be recovered and reused. Recently, a dual-reactor biological desulfurization system was implemented where an anaerobic (sulfidic) bioreactor was incorporated as an addition to a micro-oxic bioreactor, allowing for higher S selectivity by limiting by-product formation.

Integrated hydroponics systems with anaerobic supernatant and aquaculture effluent in desert regions: Nutrient recovery and benefit analysis.

Hydroponics is a resource-efficient system that increases food production and enhances the overall sustainability of agricultural systems, particularly in arid zones with prevalent water scarcity and limited areas of arable land. This study investigated zero-waste hydroponics systems fed by agricultural waste streams as nutrient sources under desert conditions. Three pilot-scale systems were tested and compared.

Polysulfide Concentration and Chain Length in the Biological Desulfurization Process: Effect of Biomass Concentration and the Sulfide Loading Rate.

Removal of hydrogen sulfide (HS) can be achieved using the sustainable biological desulfurization process, where HS is converted to elemental sulfur using sulfide-oxidizing bacteria (SOB). A dual-bioreactor process was recently developed where an anaerobic (sulfidic) bioreactor was used between the absorber column and micro-oxic bioreactor. In the absorber column and sulfidic bioreactor, polysulfides (S) are formed due to the chemical equilibrium between HS and sulfur (S).

Removal of small elemental sulfur particles by polysulfide formation in a sulfidic reactor.

For over 30 years, biological gas desulfurization under halo-alkaline conditions has been studied and optimized. This technology is currently applied in already 270 commercial installations worldwide. Sulfur particle separation, however, remains a challenge; a fraction of sulfur particles is often too small for liquid-solid separation with conventional separation technology.

Clean and Safe Drinking Water Systems Metagenomics Data and Artificial Intelligence: State-of-the-Art and Future Perspective.

The use of next-generation sequencing technologies in drinking water distribution systems (DWDS) has shed insight into the microbial communities' composition, and interaction in the drinking water microbiome. For the past two decades, various studies have been conducted in which metagenomics data have been collected over extended periods and analyzed spatially and temporally to understand the dynamics of microbial communities in DWDS. In this literature review, we outline the findings which were reported in the literature on what kind of occupancy-abundance patterns are exhibited in the drinking water microbiome, how the drinking water microbiome dynamically evolves spatially and temporally in the distribution networks, how different microbial communities co-exist, and what kind of clusters exist in the drinking water ecosystem.

Plants Dictate Root Microbial Composition in Hydroponics and Aquaponics.

The role of the microbial community in mediating fish and plant co-culture is often considered the black box of aquaponics. Despite widespread recognition regarding the dependency of plants on their rhizosphere, the extent to which upstream aquaculture influences downstream hydroponic root communities has been poorly described in the literature. In this study we performed a taxonomic survey (16S rRNA metabarcoding) of microbial communities originating in the facility water source, hydroponic nutrient solution (HNS) sump, nutrient supplemented biofilter effluent (BF) sump, and recirculating aquaculture system tanks stocked with Nile tilapia ().

Carbon dynamics and energy recovery in a novel near-zero waste aquaponics system with onsite anaerobic treatment.

Aquaponics is gaining renewed interest to enhance food security. This study aimed to investigate the performance of a novel off-grid aquaponics system with near-zero water and waste discharge, focusing on the carbon cycle and energy recovery that was achieved by the addition of onsite anaerobic treatment of the solid waste streams. Following a stabilization stage, the system was closely monitored for four months.

Selective particle separation on centimeter scale using a dual frequency dynamic acoustic field.

This study investigated the application of dual-frequency type dynamic acoustic fields for size-selective particle separation on centimeter scale in a continuous flow. The 3D-printed X-shaped prototype has two inlets and two outlets. The dynamic acoustic field is generated by two transducers positioned under an angle of 60 and operating at slightly different frequencies.

Non-steady diffusion and adsorption of organic micropollutants in ion-exchange membranes: effect of the membrane thickness.

There is no efficient wastewater treatment solution for removing organic micropollutants (OMPs), which, therefore, are continuously introduced to the Earth's surface waters. This creates a severe risk to aquatic ecosystems and human health. In emerging water treatment processes based on ion-exchange membranes (IEM), transport of OMPs through membranes remains unknown.

Biologically enhanced hydrogen sulfide absorption from sour gas under haloalkaline conditions.

We studied a biotechnological desulfurization process for removal of toxic hydrogen sulfide (HS) from sour gas. The process consists of two steps: i) Selective absorption of HS into a (bi)carbonate solution in the absorber column and ii) conversion of sulfide to sulfur by sulfide oxidizing bacteria (SOB) in the aerated bioreactor. In previous studies, several physico-chemical factors were assessed to explain the observed enhancement of HS absorption in the absorber, but a full explanation was not provided.

Development and validation of a physiologically based kinetic model for starting up and operation of the biological gas desulfurization process under haloalkaline conditions.

Hydrogen sulfide is a toxic and corrosive gas that must be removed from gaseous hydrocarbon streams prior to combustion. This paper describes a gas biodesulfurization process where sulfur-oxidizing bacteria (SOB) facilitate sulfide conversion to both sulfur and sulfate. In order to optimize the formation of sulfur, it is crucial to understand the relations between the SOB microbial composition, kinetics of biological and abiotic sulfide oxidation and the effects on the biodesulfurization process efficiency.

Selective Particle Filtering in a Large Acoustophoretic Serpentine Channel.

The objective of this study is to investigate the performance of a serpentine channel for acoustically driven selective particle filtering. The channel consists of sharp corners and straight sections, and the acoustic field is affecting the particles throughout the channel. A prototype of the separator channel is manufactured using 3D printing.

Increasing the Selectivity for Sulfur Formation in Biological Gas Desulfurization.

In the biotechnological desulfurization process under haloalkaline conditions, dihydrogen sulfide (HS) is removed from sour gas and oxidized to elemental sulfur (S) by sulfide-oxidizing bacteria. Besides S, the byproducts sulfate (SO) and thiosulfate (SO) are formed, which consume caustic and form a waste stream. The aim of this study was to increase selectivity toward S by a new process line-up for biological gas desulfurization, applying two bioreactors with different substrate conditions (i.

Glocal assessment of integrated wastewater treatment and recovery concepts using partial nitritation/Anammox and microalgae for environmental impacts.

This study explored the feasibility and estimated the environmental impacts of two novel wastewater treatment configurations. Both include combined bioflocculation and anaerobic digestion but apply different nutrient removal technologies, i.e.

Nitrogen dynamics in flooded soil systems: an overview on concepts and performance of models.

Extensive modelling studies on nitrogen (N) dynamics in flooded soil systems have been published. Consequently, many N dynamics models are available for users to select from. With the current research trend, inclined towards multidisciplinary research, and with substantial progress in understanding of N dynamics in flooded soil systems, the objective of this paper is to provide an overview of the modelling concepts and performance of 14 models developed to simulate N dynamics in flooded soil systems.

Theory of pH changes in water desalination by capacitive deionization.

In electrochemical water desalination, a large difference in pH can develop between feed and effluent water. These pH changes can affect the long-term stability of membranes and electrodes. Often Faradaic reactions are implicated to explain these pH changes.

Model of an aquaponic system for minimised water, energy and nitrogen requirements.

Water and nutrient savings can be established by coupling water streams between interacting processes. Wastewater from production processes contains nutrients like nitrogen (N), which can and should be recycled in order to meet future regulatory discharge demands. Optimisation of interacting water systems is a complex task.

Inhibition of a biological sulfide oxidation under haloalkaline conditions by thiols and diorgano polysulfanes.

A novel approach has been developed for the simultaneous description of reaction kinetics to describe the formation of polysulfide and sulfate anions from the biological oxidation of hydrogen sulfide (H2S) using a quick, sulfide-dependent respiration test. Next to H2S, thiols are commonly present in sour gas streams. We investigated the inhibition mode and the corresponding inhibition constants of six thiols and the corresponding diorgano polysulfanes on the biological oxidation of H2S.

The urban harvest approach as framework and planning tool for improved water and resource cycles.

Water and resource availability in sufficient quantity and quality for anthropogenic needs represents one of the main challenges in the coming decades. To prepare for upcoming challenges such as increased urbanization and climate change related consequences, innovative and improved resource management concepts are indispensable. In recent years we have developed and applied the urban harvest approach (UHA).

Production of volatile fatty acids from sewage organic matter by combined bioflocculation and alkaline fermentation.

This study explored the potential of volatile fatty acids (VFA) production from sewage by a combined high-loaded membrane bioreactor and sequencing batch fermenter. VFA production was optimized with respect to SRT and alkaline pH (pH 8-10). Application of pH shock to a value of 9 at the start of a sequencing batch cycle, followed by a pH uncontrolled phase for 7days, gave the highest VFA yield of 440mgVFA-COD/g VSS.

Automated biological sulphate reduction: a review on mathematical models, monitoring and bioprocess control.

In the sulphate-reducing process, bioprocess control can be used to regulate the competition between microbial groups, to optimize the input of the electron donor and/or to maximize or minimize the production of sulphide. As shown in this review, modelling and monitoring are important tools in the development and application of a bioprocess control strategy. Pre-eminent literature on modelling, monitoring and control of sulphate-reducing processes is reviewed.

Effect of Methanethiol Concentration on Sulfur Production in Biological Desulfurization Systems under Haloalkaline Conditions.

Bioremoval of H2S from gas streams became popular in recent years because of high process efficiency and low operational costs. To expand the scope of these processes to gas streams containing volatile organic sulfur compounds, like thiols, it is necessary to provide new insights into their impact on overall biodesulfurization process. Published data on the effect of thiols on biodesulfurization processes are scarce.

Volatile fatty acids production from sewage organic matter by combined bioflocculation and anaerobic fermentation.

This work aims at exploring the feasibility of a combined process bioflocculation to concentrate sewage organic matter and anaerobic fermentation to produce volatile fatty acids (VFA). Bioflocculation, using a high-loaded aerobic membrane bioreactor (HL-MBR), was operated at an HRT of 1h and an SRT of 1 day. The HL-MBR process removed on average 83% of sewage COD, while only 10% of nitrogen and phosphorus was removed.

Sulfide response analysis for sulfide control using a pS electrode in sulfate reducing bioreactors.

Step changes in the organic loading rate (OLR) through variations in the influent chemical oxygen demand (CODin) concentration or in the hydraulic retention time (HRT) at constant COD/SO4(2-) ratio (0.67) were applied to create sulfide responses for the design of a sulfide control in sulfate reducing bioreactors. The sulfide was measured using a sulfide ion selective electrode (pS) and the values obtained were used to calculate proportional-integral-derivative (PID) controller parameters.