This study investigates the effect of confinement on the phase behavior of carbon dioxide (CO) and its implications for storage in nanometer-scale pores. A patented gravimetric apparatus was employed to experimentally measure the adsorption and desorption isotherms at varying pore sizes and temperatures. The isotherms were generated at temperatures below the critical point of CO (from -23.
View Article and Find Full Text PDFThe impact of wettability on the confined phase behavior of fluids is paramount for various applications, such as gas storage, carbon dioxide sequestration, and water purification. However, the understanding of the fluid-solid intermolecular interactions in confined systems is still limited and requires further investigation. This work investigates the effect of hydrophilic and hydrophobic nanoporous materials on the adsorption and desorption isotherms of -butane.
View Article and Find Full Text PDFWe investigated the effect of confinement on the phase behavior of hexane in nanopores of mesoporous silica at varying pore diameters and temperatures using a patented gravimetric apparatus. The adsorption and desorption isotherms were experimentally measured, and the capillary condensation and evaporation pressures were calculated from the isotherms. The results show that, for all pore sizes and temperatures utilized here, the confinement of fluids significantly lowers the vapor-liquid phase transition pressures.
View Article and Find Full Text PDFFundamental understanding of the phase behavior and properties of fluids under confinement is of great significance for multiple fields of engineering and science, as well as for many practical industrial applications. In particular, unconventional geological systems, such as shale reservoirs, possess nanometer-scale pores, which impose nanoconfinement on the fluid molecules. In large pores, the bulk phase behavior of fluids can be modeled by the well-established methods, such as equation of state (EOS) approaches.
View Article and Find Full Text PDF15-40% of non-small cell lung cancer (NSCLC) patients harbor epidermal growth factor receptor (EGFR)-sensitizing mutations. Tyrosine kinase inhibitors (TKIs) provide significant clinical benefit in this population, yet all patients will ultimately progress. Liquid biopsy can reliably identify somatic tumor-associated EGFR mutations in plasma.
View Article and Find Full Text PDFAlthough it is recognized that cervical cytology is highly subjective, and that there is considerable interlaboratory variation in how slides are evaluated, little is known as to how this impacts the performance of cytology. In the ATHENA trial, liquid-based cytology specimens from 46,887 eligible women ≥21 years of age were evaluated at four large regional US laboratories, providing a unique opportunity to evaluate the impact of interlaboratory variations on the performance of cervical cytology. All women with abnormal cytology (atypical squamous cells of undetermined significance or higher) were referred to colposcopy, as were all high-risk human papillomavirus (hrHPV)-positive women ≥25 years of age and a random subset of those ≥25 years of age who were negative by both hrHPV testing and cytology.
View Article and Find Full Text PDFBackground & Objectives: Rajasthan is one of the dengue endemic states of India. Very few studies have been published on entomological aspects of dengue in this state. Owing to water scarcity, inhabitants in desert areas overstore domestic water which leads to the persistence of dengue vectors within the domestic premises.
View Article and Find Full Text PDFImmature Aedes mosquitoes were found in domestic, peridomestic, and tree hole habitats within three socioeconomic strata of Jodhpur, a city within an arid area of Rajasthan, India, endemic for dengue. Peridomestic habitats served as a persistent source of Aedes vectors, especially those used for watering cows for religious reasons that were located within high socioeconomic areas. Domestic (indoor) containers within low socioeconomic strata showed a higher container index (27.
View Article and Find Full Text PDFBackground & Objectives: Malaria is the major health problem in western Rajasthan yet its vector fauna and transmission dynamics thereof is not understood properly. The present investigations report complete profile of qualitative and quantitative aspects of anopheline species occurring in different settings of desert ecosystem.
Methods: Area with irrigation through canal for more than 20 years (setting I), area with irrigation through canal for 10 years (setting II) and area without any irrigation (setting III) have been selected for studies.