Synthesis of α-Trifluoromethylated Ketones from α,β-Unsaturated Ketones via Catecholboron Enolates.

Herein, we report a protocol for the synthesis of α-trifluoromethylated ketones through trifluoromethylation of the corresponding catecholboron enolates of α,β-unsaturated ketones. The reaction of the 1,4-hydroborated product of enones with the Togni II reagent affords the α-trifluoromethylated ketones without any catalyst or additive. Moreover, the protocol has been employed on a series of α,β-unsaturated ketones, including chalcones, substrate-bearing heterocycles, and bioactive molecules.

Evidence of microplastics in the polychaete worm (capitellids-Capitella capitata) (Fabricicus, 1780) along Thoothukudi region.

Research on the occurrence of microplastics in invertebrates of the Thoothukudi region is limited. Capitellids are non-selective suspension feeders and are usually used as bioindicator of water pollution. Hence, an investigation was carried out to identify the microplastic occurrence in the capitellids (Capitella capitata) (Fabricius, 1780) collected from the Vellapatti and Spic Nagar sites of the Thoothukudi region.

Chitosan-Based Biomaterial in Wound Healing: A Review.

Wound healing is an evolving and intricate technique that is vital to the restoration of tissue integrity and function. Over the past few decades, chitosan a biopolymer derived from chitin, became known as an emerging biomaterial in the field of healing wounds due to its distinctive characteristics including biocompatibility, biodegradability, affinity to biomolecules, and wound-healing activity. This natural polymer exhibits excellent healing capabilities by accelerating the development of new skin cells, reducing inflammation, and preventing infections.

A Metal-Free and Operationally Simple Radical Trifluoromethylative Borylation of Unactivated Alkenes.

We herein describe a protocol to synthesize trifluoromethylated alkyl boronates from alkenes by the mutual activation of the Togni II and the bis(catecholato)diboron reagents in the absence of any catalyst and additives. This reaction enables synthesizing a series of trifluoromethylated alkyl boronates using unactivated alkenes, including natural products and drug derivatives, in a regioselective manner. Moreover, the synthetic utility of the boronic ester present in the product allows access to a range of trifluoromethyl containing compounds.

Ingestion of microplastics in commercially important species along Thoothukudi coast, south east India.

Microplastics pollute the marine environment and pose a greater risk to marine organisms. The microplastics were observed in the guts of the 12 species, which varied from 0.00 to 1.

Microplastics accumulation in pelagic and benthic species along the Thoothukudi coast, South Tamil Nadu, India.

Microplastics contamination poses a serious threat to marine biota, so the current study was carried out to assess the incidence of microplastics in the gastrointestinal tracts of pelagic and benthic species collected from the six sampling sites along Thoothukudi region from January 2021 to December 2021. In the present study, benthic species (0.67 ± 0.

Spatial, seasonal and ecological risk assessment of microplastics in sediment and surface water along the Thoothukudi, south Tamil Nadu, south east India.

Microplastics are a widespread environmental contaminant that raises serious concern for aquatic organisms. Hence, the present study was conducted to investigate the spatial and seasonal variation of microplastics, their characteristics, polymer types and the risk assessment caused by the microplastics in six sampling sites along the Thoothukudi region. The average microplastic abundance ranged from 32 ± 26 to 232 ± 229 items/kg and 54 ± 41 to 619 ± 377 items/l in sediment and surface water, respectively, and they exhibited a significant spatial difference among the sampling sites.

Contamination of microplastics, surface morphology and risk assessment in beaches along the Thoothukudi coast, Gulf of Mannar region.

Microplastics accumulation on beaches raises a serious concern worldwide. Hence, the present study was conducted with the focus of investigating the abundance, characteristics, risk assessment, surface morphology and elemental composition of microplastics (MPs) in the beach sediments of the Thoothukudi region, situated on the south-east coast of India, Gulf of Mannar region. The MPs abundance ranged between 19 ± 18.