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View Article and Find Full Text PDFWastewater management has become necessary in this industrialized era to meet the water needs of the world. Wastewater is one of the major crises in depletion of the environment. Photocatalysis is considered as the best way to remove pollutants.
View Article and Find Full Text PDFThis study demonstrates the direct conversion of vinylogous esters into selectively protected 6-acyl resorcinols (4-alkoxy/aryloxy-2-hydroxy arylketones) in a regiospecific manner. Resorcinyl ketones are first-time synthesized, diverging from their traditional roots, originating from non-benzenoid pool materials. Converting cyclohexenones into phenol- or resorcinol-based arylketones remains challenging due to the stability and reactivity issues of intermediate products.
View Article and Find Full Text PDFBackground: The National TB elimination programme (NTEP) is facilitating sub-national certification of "TB Free" status with benchmarks at every 20% reduction in incidence from the baseline of 2015. Drug consumption/sale is essential criteria to claim for the award. During the certification process in 10 districts of Madhya Pradesh in 2022, it was found that Nikshay Aushadhi (a web-based supply chain management portal) entries were incomplete or vacant in most of the districts and it was observed that quarterly drug requests were not sent using Nikshay Aushadhi.
View Article and Find Full Text PDF(1) Background: To compare the degree of conversion of resin cores in various types of cavities and determine an effective irradiation method for achieving a higher degree of conversion. (2) Methods: Four different-sized cavities (narrow-shallow, narrow-deep, wide-shallow, and wide-deep) were simulated using a Teflon mold. The light irradiance reaching the bottom of each mold was measured by positioning a radiometer.
View Article and Find Full Text PDFSolid phase microextraction (SPME) has emerged as a versatile sample preparation technique for the preconcentration of a broad range of compounds with various polarities, especially in environmental studies. SPME has demonstrated its eco-friendly credentials, significantly reducing the reliance on solvents. The use of biocompatible materials as a coating recipe facilitates the acceptance of SPME devices in analytical chemistry, primarily in the monitoring of environmental pollutants such as persistent organic pollutants (POPs), volatile organic compounds (VOCs), and pesticides from the various environmental matrices.
View Article and Find Full Text PDFHuman skin emits a series of volatile compounds from the skin due to various metabolic processes, microbial activity, and several external factors. Changes in the concentration of skin volatile metabolites indicate many diseases, including diabetes, cancer, and infectious diseases. Researchers focused on skin-emitted compounds to gain insight into the pathophysiology of various diseases.
View Article and Find Full Text PDFThe present study validates the impact of nickel oxide nanoparticles (NiONPs) biosynthesized from the brown seaweed Dictyota bartayresiana (DB) and its biological applications. The phytochemicals analyzed in the seaweed extract served as a reducing, capping or stabilizing agent in the formation of nanoparticles. UV visible spectrum of nickel oxide nanoparticles synthesized from DB (DB-NiONPs) represented a prominent peak at 392 nm which validates its formation.
View Article and Find Full Text PDFHydrothermal synthesis of pristine and Sr doped TiO is proposed. The synthesized products were studied for their physiochemical properties. 3% Sr-TiO showed a narrow bandgap, which facilitate an increase in oxygen vacancies.
View Article and Find Full Text PDFAnnually, India contributes to one-fifth of newly diagnosed pediatric cancers worldwide. Poor outcome in India as compared with developed nations is mainly attributed to delayed diagnosis and study of factors influencing delay in diagnosis holds paramount importance in formulating strategies and counter-measures to improve survival. It was a cross-sectional study conducted on children diagnosed with malignancy at a tertiary care hospital.
View Article and Find Full Text PDFA biomimetic bilayer lipid membrane supported MXene based biosensor is reported for electrochemical hybridization detection of the most prevalent and potential BC biomarker BRCA1. 2D MXene nanosheet-anchored gold nanoparticle-decorated biomimetic bilayer lipid membrane (AuNP@BLM) biosensor is used for the attachment of thiolated single-stranded DNA (HS-ssDNA) targeting hybridization detection. The interaction of biomimetic bilayer lipid membrane with 2D MXene nanosheets is explored in this work for the first time.
View Article and Find Full Text PDFIndian J Community Med
October 2022
Background: The term mucormycosis refers to any fungal infection caused by fungi belonging to the Mucorales order. The disease often manifests in the skin and also affects the lungs and the brain. A large number of Mucormycosis cases were detected in Delhi, Maharashtra and Gujarat, and Madhya Pradesh.
View Article and Find Full Text PDFAn innovative and ultrasensitive electrochemical impedimetric immunosensor was developed for the quantitative detection towards carcinoembryonic antigen (CEA). CEA is a widely utilized tumour biomarker that is generated in a wide variety of cancers and it is a frequently used biomarker for clinical research and early detection of cancer. Novelty of the present work is the utilization of biomimetic membrane comprising gold nanoparticle-stabilized lipid bilayer (SLB) containing DOPE (1,2-dioleoyl-sn-glycero-3-phosphoethanolamine) and DOTAP (N-[1-(2,3-Dioleoyloxy)propyl]-N,N,N-trimethyl ammonium Propane) for easy protein insertion, bio-affinity, and bio-functionalization towards the detection of CEA.
View Article and Find Full Text PDFConversion and reducing agent (NaBH) effect on zero valent iron into FeO nanoparticles with diverse molar ratios of reducing agent was produced through chemical reduction technique. The structural, optical, vibrational analyses were executed via XRD, UV-Vis, Raman, and FT-IR analysis. The crystallite size obtained were 35 nm, 27 nm, and 18 nm for Fe:NaBH (1:1), Fe:NaBH (1:2) and Fe:NaBH (1:3).
View Article and Find Full Text PDFPristine and Mn-TiO photocatalysts was prepared employing sophisticated hydrothermal technique. TiO, 0.2 M, 0.
View Article and Find Full Text PDFHerein, we reported the synthesis of BiOX (X = Cl, Br) with different grinding time like 15 min and 30 min to analyze the evolution of physiochemical properties and the morphological evolution. The structural, optical, vibrational properties were examined by standard characterization studies. The formation of bismuth oxyhalides were confirmed by XRD and Raman studies.
View Article and Find Full Text PDFThe present study discusses the ammonia (NH) sensing characteristics, photocatalytic degradation of emerging pollutants, and peroxidase mimic activity of multifunctional multi-walled carbon nanotube-tungsten oxide nanocomposite (MWCNT/WO) prepared by conventional solvothermal method. The prepared MWCNT/WO nanocomposites were characterized by various analytical techniques like XRD, Raman, XPS, N adsorption, FESEM with elemental analysis and diffuse reflection spectroscopy. The prepared 1% MWCNT/WO nanocomposite showed better gas sensing performance for the NH vapors at 10-100 ppm than the pristine WO and the response and recover time of about 13 and 15s towards 20 ppm of ammonia (NH) was achieved.
View Article and Find Full Text PDFIn this study, pristine β-CuVO, CTAB-β-CuVO and PVP-CuVO were synthesized via hydrothermal method. The synthesized brown powder samples were exemplified using XRD, UV, PL, Raman and SEM studies. Further with XRD, we confirmed that the impurities were eradicated in addition of surfactant PVP.
View Article and Find Full Text PDFA new 2D transition metal carbides family noted that MXene with antimony (Sb) nano-needles composites have demonstrated potential applications for photocatalytic dye degradations applications. Single-step synthesis of novel structures two/one-dimensional MXene@antimony nanoneedle (MX@Sb-H) nanocomposite-based photocatalysts is produced employing hydrothermal technique. The preparations and characterizations were compared with hand mixture preparations of pure TiO@Sb and MXene (MX@Sb-M).
View Article and Find Full Text PDFPristine and Ce doped TiO nanoparticles were fabricated for toxic pollutants removal from wastewater. Pristine, 2% Ce and 4% Ce doped TiO photocatalysts were produced via hydrothermal route. 4% Ce doped TiO exhibited 2.
View Article and Find Full Text PDFA facile synthesis of pristine and g-CN loaded CdWO (Cadmium Tungstate) were reported and analyzed the effect of pollutants removal in wastewater. The samples were characterized and the morphology of the pristine sample showed the nanostructures with high cluster of layer formed. While adding PEG (Polyethylene glycol), the surface has exhibited less agglomeration and in g-CN added sample the agglomeration was intensely reduced and nanostructures have been clearly found.
View Article and Find Full Text PDFAim: The Aim of the study was to evaluate the reproducibility of condylar inclination values obtained using three different interocclusal recording materials in Hanau Wide-Vue semi-adjustable articulator and to compare those values of condylar inclination with panoramic radiographic images.
Settings And Design: In Vivo Comparative study.
Materials And Methods: The clinical trial was carried out in the Department of Prosthodontics, M.
Treatment of wastewater for reuse is an important strategy undertaken to deal with water scarcity. In this study, pure and La-doped barium ferrites were produced using a facile hydrothermal technique. Lanthanum was doped at 1% and 2% molar ratio and the obtained product was analyzed for further confirmation of crystal structure, optical properties, vibrational properties, and morphology.
View Article and Find Full Text PDFPristine and polyethylene glycol assisted antimony tungstate (SbWO) was developed via hydrothermal route. The pristine and surfactant assisted SbWO were further exemplified to reveal the properties of the samples. The bandgap calculated for SbWO, 5 ml PEG- SbWO, 10 ml PEG- SbWO was 2.
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