Publications by authors named "Kechao Wang"

Article Synopsis
  • Three porous zirconium-based metal-organic frameworks (MOFs) — UiO-66, MOF-808, and MOF-802 — were tested for their ability to catalyze the oxidation of cyclohexane to understand what makes each effective.
  • It was discovered that decreasing the number of ZrO linkages improved the catalytic efficiency, likely due to better enrichment of cyclohexane in the MOFs with fewer linkages.
  • MOF-802 showed lower catalytic performance than expected because of its low porosity and narrow pores, and various by-products from the reaction were identified, supporting the study’s findings on the catalytic mechanism and showing the potential for industrial application.
View Article and Find Full Text PDF

A yolk-shell Au NPs@carbon porous nanoreactor with an active gold (Au) core and a porous carbon shell has been fabricated and demonstrates excellent high activity and cyclic stability as a heterogeneous catalyst for the three-component coupling reaction of aldehyde, amine, and alkyne. Remarkably, the unique yolk-shell nanostructure can protect gold nanoparticles (Au NPs) from aggregation, allow for efficient mass transport, and benefit substrate enrichment, giving rise to enhanced activity, stability, and recyclability.

View Article and Find Full Text PDF

Cropland encroachment on protected areas causes natural habitat loss, which may damage ecosystem functions and biodiversity conservation, leading to trade-offs between crop production and habitat conservation. Here we investigate the sustainable utilization and effects of cropland within protected areas, on which we make trade-offs with an established framework. Analyses show that 3.

View Article and Find Full Text PDF

Understanding the spatiotemporal dynamics of global 3D urban expansion over time is becoming increasingly crucial for achieving long-term development goals. In this study, we generated a global dataset of annual urban 3D expansion (1990-2010) using World Settlement Footprint 2015 data, GAIA data, and ALOS AW3D30 data with a three-step technical framework: (1) extracting the global constructed land to generate the research area, (2) neighborhood analysis to calculate the original normalized DSM and slope height of each pixel in the study area, and (3) slope correction for areas with a slope greater than 10° to improve the accuracy of estimated building heights. The cross-validation results indicate that our dataset is reliable in the United States(R = 0.

View Article and Find Full Text PDF

Farmland abandonment, a widespread phenomenon during land-use transition, leads to a cycling or vanishing evolution of farmland resources. As urbanization advances, an increasing number of agricultural laborers migrate from rural to urban areas, causing ongoing farmland abandonment. However, in contrast to the abandoned information extraction and driving mechanisms revelation, the potential risk of farmland abandonment has received insufficient attention.

View Article and Find Full Text PDF

Cervical cancer is one of the main causes of cancer death all over the world. Most diseases such as cervical epithelial atypical hyperplasia and invasive cervical cancer are closely related to the continuous infection of high-risk types of human papillomavirus. Therefore, the high-risk types of human papillomavirus are the key to the prevention and treatment of cervical cancer.

View Article and Find Full Text PDF

Despite the advancement in the diagnosis and therapeutic strategies for colorectal cancer, the outcomes of patients with colorectal cancer remain unsatisfactory. Alisol A is a natural constituent of Alismatis rhizoma (zexie) and has demonstrated anti-cancer properties; however, the function of Alisol A in colorectal cancer is still unknown. In the present study, the effect of Alisol A on colorectal cancer progression was investigated.

View Article and Find Full Text PDF

Catalytic fast pyrolysis experiments of low-density polyethylene (LDPE) over HZSM-5 were carried out by using infrared heating technology. The effects of heating rate (1-30 °C/s), pyrolysis temperature (450-650 °C), and mass ratio of catalyst to LDPE (0:100 to 50:100) on product distribution and oil composition in LDPE pyrolysis were investigated, and the fast pyrolysis mechanism was explored. The results indicated that a higher heating rate, namely 20 °C/s, can remarkably enhance the liquid oil yield (93.

View Article and Find Full Text PDF

Because of the complex and fine structure, visualization of the heart still remains a challenging task, which makes it an active research topic. In this paper, we present a visualization system for medical data, which takes advantage of the recent graphics processing unit (GPU) and can provide real-time cardiac visualization. This work focuses on investigating the anatomical structure visualization of the human heart, which is fundamental to the cardiac visualization, medical training and diagnosis assistance.

View Article and Find Full Text PDF