From Block Copolymer Nanotubes to Nanospheres: Nonsolvent-Induced Morphology Transformation Using Porous Templates.

Block copolymer nanostructures have attracted great attention because of the wide range of applications such as sensors and drug delivery. The fabrication of block copolymer nanostructures with controlled morphologies and sizes, however, is still challenging. Here, we study the fabrication of nanotubes and nanospheres of polystyrene- block-polybutadiene (PS- b-PBD) using anodic aluminum oxide (AAO) templates.

Fabrication of Core-Shell Polymer Nanospheres in the Nanopores of Anodic Aluminum Oxide Templates Using Polymer Blend Solutions.

Spherical core-shell structures have been widely investigated in recent years, and they can be used for various applications, such as drug delivery, biological labeling, and batteries. Although many methods have been developed to prepare core-shell structures, it is still a great challenge to fabricate core-shell structures in the nanoscale with well-controlled morphologies and sizes. In this work, we present a simple method to fabricate core-shell polymer nanospheres consisting of polystyrene (PS) cores and poly(methyl methacrylate) (PMMA) shells.