Dual mode OPV-OLED device with photovoltaic and light-emitting functionalities.

The rapid development of organic optoelectronic devices such as organic photovoltaics (OPVs) and organic light-emitting devices (OLEDs) is largely attributable to their advantageous properties of their large area, ultrathin thickness, flexiblility, transparency, and solution processability. Herein, we fabricate and characterize a dual mode OPV-OLED device with three-terminal structure comprising a polymer-based bulk-heterojunction inverted OPV unit and a top-emission white phosphorescent OLED unit back-to-back connected via intermediate metal alloy electrode. Sputter-deposited indium tin oxide was used as a transparent cathode of the inverted OPV unit, whereas Ag-doped Al served as a common OPV/OLED anode, allowing the decoupling of electricity generation and light mission functions.

Low-driving-voltage blue phosphorescent organic light-emitting devices with external quantum efficiency of 30%.

A homoleptic iridium (iii) tris(pheny-limidazolinate) complex realizes a high EQE of 30%, a low turn-on voltage of 2.5 V, and a small efficiency roll-off in a blue organic light-emitting device (OLED). This device also shows high power efficiencies over 75 lm W(-1) and an ideal light distribution pattern at 100 cd m(-2).